Particle electrode catalyst filling for three-dimensional electrode and preparation method thereof
A particle electrode, three-dimensional electrode technology, applied in chemical instruments and methods, oxidized water/sewage treatment, water/sewage treatment, etc., can solve the problem of affecting the effect and quantity of catalyst active centers, affecting the efficiency of organic pollutant treatment, and insufficient synergy effect It can achieve the effects of low energy consumption and maintenance costs, broad application prospects, and significant economic benefits.
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Embodiment 1
[0023] Calculated by weight percentage, with 50% activated carbon as the matrix, 13% iron oxide, 12% copper oxide, 4% manganese oxide, 1% zinc oxide, 0.5% zirconia, 0.5% cerium oxide as the initiator, and 19% wood Calcium Sulfonate is used as the binder, add water and mix evenly, then extrude and cut into pellets, then dry naturally, and finally heat carbonization and activation for 2 hours under the condition of 430°C and anoxic, and make a particle size of 4-6mm particle electrodes.
Embodiment 2
[0025] Calculated by weight percentage, with 50.5% activated carbon as the matrix, 13.5% iron oxide, 12.5% copper oxide, 4% manganese oxide, 1.2% zinc oxide, 0.6% zirconia, 0.7% cerium oxide as the initiator, and 17% wood Calcium sulfonate is used as the binder and mixed with water, then extruded and cut into pellets, then air-dried, and finally heated and carbonized and activated for 3 hours under the condition of 470°C and anoxic, and made into particles with a particle size of 4-6mm. particle electrodes. Fill the particle electrode with the synthesized catalyst packing, under the conditions of air flow rate 60L / h, voltage 30V, pH4.27 and reaction time 10-60min, COD Cr The treatment effect of potassium hydrogen phthalate wastewater is 618mg / L. And under the same conditions, compared with the treatment effect of using traditional three-dimensional electrode catalyst packing (old packing). The result is as figure 2 As shown, this shows that compared with the traditional ...
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