Aqueous adhesive for shoes and its production method

A technology for adhesives and shoes, applied in the directions of adhesives, adhesive types, ester copolymer adhesives, etc., can solve the problems of high production cost, shortage, limited production and use scope, etc., to reduce raw material costs and achieve excellent elasticity. , the effect of improving the drying speed

Inactive Publication Date: 2007-07-11
广州化工研究设计院有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The bonding performance and application process of water-based polyurethane shoe glue are the same as those of solvent-based shoe glue. Some large foreign companies, such as Bayer in Germany, Wyanclotte in the United States, Ink companies, etc., they have produced various brands of water-based polyu

Method used

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  • Aqueous adhesive for shoes and its production method

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0041] Example one:

[0042] First, the preparation of polyacrylate emulsion.

[0043] Polyacrylate emulsion components and weight percentage:

[0044] Deionized water 34.2% acrylic acid 0.5%

[0045] Butyl acrylate 38% Methyl methacrylate 23%

[0046] Isooctyl acrylate 1% Hydroxyethyl acrylate 0.5%

[0047] Emulsifier 2% Buffer 0.2%

[0048] Reducing agent 0.1% Initiator 0.5%

[0049] Prepare the polyacrylate emulsion as follows:

[0050] 1) Emulsification: dissolve the emulsifier in deionized water, add butyl acrylate, acrylic acid, isooctyl acrylate and methyl methacrylate under stirring, and stir and emulsify to obtain a monomer emulsion.

[0051] 2) Prepolymerization: Dissolve the buffer in non-ionized water in the reactor, add a small amount (5%) of monomer emulsion, heat up to polymerization temperature (85°C), add a solution of reducing agent and initiator (50%) , Prepare seed emulsion.

[0052] Three) Polymerization: Drop the remaining monomer emulsion and the remaining (...

Example Embodiment

[0060] Embodiment two:

[0061] First, the preparation of polyacrylate emulsion.

[0062] Polyacrylate emulsion components and weight percentage:

[0063] Deionized water 34.2% acrylic acid 0.5%

[0064] Butyl acrylate 38%, methyl methacrylate 23%,

[0065] Isooctyl acrylate 1%, hydroxyethyl acrylate 0.5%,

[0066]Emulsifier 2%, buffer 0.2%,

[0067] The reducing agent is 0.1%, and the initiator is 0.5%.

[0068] The preparation method of polyacrylate emulsion is the same as in Example 1.

[0069] Second, prepare water-based adhesive for shoes:

[0070] Formula components and weight percentage:

[0071] Polyacrylate emulsion 20%, take 20KG,

[0072] Taiwan's U-88 water-based polyurethane emulsion 76% (commodity), take 76KG,

[0073] Acetone 3%, take 3KG,

[0074] Thickener 1%, take 1KG.

[0075] The preparation method is the same as in Example 1.

Example Embodiment

[0076] Embodiment three:

[0077] First, the preparation of polyacrylate emulsion.

[0078] Polyacrylate emulsion components and weight percentage:

[0079] Deionized water 34.2% acrylic acid 0.5%

[0080] Butyl acrylate 38%, methyl methacrylate 23%,

[0081] Isooctyl acrylate 1%, hydroxyethyl acrylate 0.5%,

[0082] Emulsifier 2%, buffer 0.2%,

[0083] The reducing agent is 0.1%, and the initiator is 0.5%.

[0084] The preparation of polyacrylate emulsion is the same as in Example 1.

[0085] Second, prepare water-based adhesive for shoes:

[0086] Formula components and weight percentage:

[0087] Polyacrylate emulsion 16%, take 16KG,

[0088] Taiwan U-66 water-based polyurethane dispersion 80% (commodity), take 80.7KG,

[0089] Acetone 3%, take 3KG,

[0090] Thickener 0.3%, take 0.3KG.

[0091] The preparation method is the same as in Example 1.

[0092] The above-mentioned water-based adhesive for shoes has been formulated and used, and its technical indicators are as follows:...

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Abstract

The invention discloses an aqueous adhesive of shoe and manufacturing method in the shoe adhesive domain, which comprises the following parts: 8-20% polyacrylacid ester emulsion, 75-90% aqueous polyurethane emulsion, 0-3% acetone and 0.2-1% thickener, wherein the polyacrylacid ester emulsion is composed of butyl acrylate, methyl methacrylate, acrylic acid isooctanoic ester, ethyl acrylate, acrylic acid, emulsifier, buffer, reducer and initiator. The manufacturing method comprises the following steps: emulsifying; prepolymerizing; polymerizing; neutralizing; blending.

Description

Technical field: [0001] The invention belongs to the field of adhesives for shoes, and in particular relates to a water-based adhesive used in the shoemaking industry and a production method thereof. Background technique: [0002] There are billions of people in the world, and everyone needs to wear shoes. China has 1.3 billion people. It is the country with the largest number of people who wear shoes in the world, and it is also the largest country in the shoe industry. There are more than 20,000 shoe-making enterprises in my country. At home, most manufacturers use adhesives to produce shoes. Adhesives are mainly divided into two categories: solvent-based shoe glue and water-based shoe glue. The annual consumption of shoe adhesives reaches more than 200,000 tons, but most of them are solvent-based shoe glues. With the increasing awareness of environmental protection, relevant laws and regulations will become increasingly stringent. Water-based shoe glues that do not pollute...

Claims

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Application Information

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IPC IPC(8): C09J175/04C09J133/08C09J9/00A43B13/32
Inventor 朱炳华叶家灿林汉昭潘滴云林华玉
Owner 广州化工研究设计院有限公司
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