Corrosion protection for lubricants

a technology of corrosion protection and lubricants, applied in the field of corrosion protection of lubricants, can solve the problems of s, p-containing additives, p-containing additive systems, and difficult for formulators to use s, so as to avoid corrosion of copper

Inactive Publication Date: 2006-10-26
EXXONMOBIL CHEM PAT INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0015] The lubricant composition of the invention comprises a combination of at least one triazole-containing species and at least one species selected from a thiadiazole-containing species. In embodiments the invention provides improved corrosion protection for manual transmissions.
[0017] In even more preferred embodiments, lubricant compositions comprising alkyl polysulfides and alkyl phosphate esters, in combination with a triazole-containing corrosion inhibitor, such as tolyl triazole and dimercaptothiadizole, have been found particularly effective in avoiding corrosion of copper.
[0021] It is another object of the invention to provide a lubricant formulation based on S, P chemistry that provides high temperature copper corrosion resistance.

Problems solved by technology

However, corrosion may be seen in the field with the use of S, P-based lubricants, particularly when copper-containing components, e.g. coolers, are employed.
Consequently, OEMs are issuing specifications which make it difficult for formulators to use S, P-containing additives.
Therefore, many have stopped using S, P-containing additive systems because of corrosion issues.
New demands with respect to micropitting, corrosion protection and durability are placing severe demands even on MTOs not using S, P chemistry.
Conventional S, P packages struggle to meet a satisfactory level of performance.
Given the enormous number of ingredients proposed for additive packages, it is a formidable task to find the right combination capable of meeting the number of new requirements desired in driveline fluids such as MTOs while maintaining traditional performance standards in other areas.

Method used

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Embodiment Construction

[0024] According to the invention, a lubricant composition is provided comprising a combination of at least one triazole, triazole derivative, or salt thereof, referred to herein as “triazole-containing species”, and at least one species selected from a thiadiazole-containing species.

[0025] In embodiments, the lubricant composition will also include ingredients selected from: at least one extreme pressure (EP) component selected from sulfur-containing and / or boron-containing species; and at least one phosphorus-containing antiwear component.

[0026] In embodiments comprising at least one sulfur-containing EP component, a preferred lubricant composition is characterized by a mass ratio of sulfur to triazole-containing species of less than or equal to 150:1.

[0027] Additional embodiments are described herein below.

[0028] Critical ingredients are selected from the following materials.

[0029] A. Triazole-Containing Species.

[0030] A key ingredient in the lubricant composition according...

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Abstract

The present invention relates to compositions comprising at least one triazole-containing species and at least one thiadiazole-containing species, which in embodiments are suitable for manual transmission oils.

Description

CROSS REFERENCE TO RELATED APPLICATION [0001] This application claims the benefit of Provisional Application No. 60 / 673,858 filed Apr. 22, 2005, the disclosure of which is incorporated by reference.FIELD OF THE INVENTION [0002] The invention relates to lubricating compositions and other functional fluids. The compositions comprise at least one triazole-containing species and at least one thiadiazole-containing species. In preferred lubricating compositions, at least one extreme pressure (EP) component and at least one phosphorus-containing antiwear component are also present. In preferred embodiments the compositions are particularly useful in manual transmission oils. BACKGROUND OF THE INVENTION [0003] Emerging industry requirements for manual transmission fluids in the areas of micropitting and corrosion protection have created a need for new lubricant compositions. In order to meet these requirements, new additive systems suitable for blending with appropriate base stocks are nee...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10M135/32
CPCC10M141/08C10M141/10C10N2260/14C10M141/12C10M169/04C10M169/044C10M2205/0206C10M2205/0265C10M2215/04C10M2215/223C10M2215/225C10M2215/28C10M2219/022C10M2219/106C10M2223/04C10M2223/041C10N2220/00C10N2220/022C10N2230/06C10N2230/12C10N2240/04C10N2240/044C10N2240/08C10N2020/00C10N2020/02C10N2030/06C10N2030/12C10N2040/04C10N2040/044C10N2040/08C10N2060/14
Inventor SULLIVAN, WILLIAMWU, SHI-MINGBRANDES, ELLEN B.
Owner EXXONMOBIL CHEM PAT INC
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