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Systems and Methods Implementing Layers of Devitrified Metallic Glass-Based Materials

a technology of devitrification and glass-based materials, applied in the direction of coatings, layered products, chemistry apparatus and processes, etc., can solve the problems of limited thickness with which metallic glasses could be formed, limited viability of engineering materials, and initial largely limited limitations of metallic glasses

Inactive Publication Date: 2017-08-10
CALIFORNIA INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a method for creating layers of devitrified metallic glass-based materials using a liquid phase metallic glass. The method involves applying the liquid phase metallic glass to an object and solidifying it to form a solid phase devitrified metallic glass-forming coating. The coating can be nanocrystalline or have a higher hardness and stiffness than the underlying object. The method can be used on a variety of objects made of metal, polymer, ceramic, or glass, and can be carried out under vacuum or inert environment. The technical effects of the invention include improved mechanical properties, enhanced corrosion resistance, and improved surface smoothness of the coated object.

Problems solved by technology

Nonetheless, the manufacture and implementation of metallic glasses present challenges that limit their viability as engineering materials.
The first metallic glasses required extraordinary cooling rates, e.g. on the order of 106 K / s, to avoid crystallization, and were thereby limited in the thickness with which they could be formed because thicker parts could not be cooled as quickly.
Indeed, because of this limitation in thickness, metallic glasses were initially largely limited to applications that involved coatings.

Method used

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Embodiment Construction

[0056]Turning now to the drawings, systems and methods for implementing layers of devitrified metallic glass-based materials are illustrated. In many embodiments the systems and methods comprise dipping an object into a molten reservoir of a metallic glass-based material to form a layer on a portion of the object, and cooling the layer of metallic glass-based material at a rate slow enough to ensure devitrification of the material.

[0057]For the purpose of this invention, amorphous metal is a multi-component metal alloy that exhibits an amorphous (non-crystalline) atomic structure. These alloys can also be called metallic glasses, as they exhibit a glass transition temperature. A de-vitrified metallic glass is one that has a fully or mostly crystalline structure either due to insufficient cooling from the liquid or from heating with the intent of crystallization. For the purposes of this patent application, the term ‘metallic glass-based material’ shall be interpreted to be inclusive...

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Abstract

Systems and methods in accordance with embodiments of the invention implement layers of devitrified metallic glass-based materials. In one embodiment, a method of fabricating a layer of devitrified metallic glass includes: applying a coating layer of liquid phase metallic glass to an object, the coating layer being applied in a sufficient quantity such that the surface tension of the liquid phase metallic glass causes the coating layer to have a smooth surface; where the metallic glass has a critical cooling rate less than 106 K / s; and cooling the coating layer of liquid phase metallic glass to form a layer of solid phase devitrified metallic glass.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]The current application claims priority to U.S. Provisional Application No. 62 / 293,210, filed Feb. 9, 2016, the disclosure of which is incorporated herein by reference.STATEMENT OF FEDERAL FUNDING[0002]The invention described herein was made in the performance of work under a NASA contract NNN12AA01C, and is subject to the provisions of Public Law 96-517 (35 U.S.C. 202) in which the Contractor has elected to retain title.FIELD OF THE INVENTION[0003]The present invention generally regards layers of devitrified metallic glass-based materials, and techniques for fabricating such layers.BACKGROUND[0004]Metallic glasses, also known as amorphous metals, have generated much interest for their potential as robust engineering materials. Metallic glasses are characterized by their disordered atomic-scale structure in spite of their metallic constituent elements—i.e. whereas conventional metallic materials typically possess a highly ordered atomic s...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C23C2/28C22C45/00C22C45/10C21D1/18
CPCC23C2/28C21D1/18C22C2200/02C22C45/10C21D2201/03C22C45/001B32B15/01C22C45/00C22C45/02C22C45/04C22C1/11C23C2/29
Inventor HOFMANN, DOUGLAS C.
Owner CALIFORNIA INST OF TECH
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