Copper-contained mixed transition metal thiophosphite and its preparation process and application

A technology of metal thiophosphite and transition metal ions, applied in the direction of phosphorus sulfur/selenium/tellurium phosphorus compounds, etc., to achieve excellent conductivity and broaden the research scope

Inactive Publication Date: 2008-06-18
WUHAN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Examples

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Embodiment 1

[0015] Example 1; Mn 0.85 Cu 0.27 P 0.94 S 3 Synthesis: 0.30g (1.65mmol) MnPS 3 With 0.09g (0.45mmol) Cu(CH 3 COO) 2 ·H 2 O was added to a reaction flask containing 10 mL of distilled water, reacted at 65°C for 7 days, filtered after cooling, washed the solid with water and ethanol for 2-3 times in turn, dried and weighed to obtain 0.31 g of the product. Elemental analysis results: Mn, 24.60%, Cu, 8.95%; P, 14.61%. The conductivity at room temperature is 6.9×10 -4 S / cm.

Embodiment 2

[0016] Example 2: Mn 0.54 Cu 1.03 P 0.71 S 3 Synthesis: 0.30g (1.65mmol) MnPS 3 With 0.33g (1.65mmol) Cu(CH 3 COO) 2 ·H 2 O was added to a reaction flask containing 10 mL of distilled water, reacted at 65°C for 7 days, filtered after cooling, washed the solid with water and ethanol for 2-3 times, dried and weighed to obtain 0.32 g of the product. Elemental analysis results: Mn, 21.34%; Cu, 30.08%; P, 9.58%. The conductivity at room temperature is 7.6×10 -2 S / cm.

Embodiment 3

[0017] Example 3: Mn 0.78 Cu 0.54 P 0.84 S 3 Synthesis: 0.30g (1.65mmol) MnPS 3 With 0.16g (0.80mmol) Cu(CH 3 COO) 2 ·H 2 O was added to a reaction flask containing 10 mL of distilled water, reacted at 20°C for 30 days, filtered after cooling, washed the solid with water and ethanol for 2-3 times, dried and weighed to obtain 0.30 g of the product. Elemental analysis results: Mn, 21.03%; Cu, 16.52%; P, 12.85%. The conductivity at room temperature is 5.8×10 -3 S / cm.

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Abstract

A thiophosphite of Cu contained transition metal mixture has a chemical formula CuxMyP2S3, where M is Mn, Fe, Ni and Cd, x=0-1.5, y=0-1.0 and z=0.5-1.0. It has excellent electric conductivity and can be used to prepare the intercalation compound and multifunctional molecular material with high photoelectric activity. Its preparing process is also disclosed.

Description

technical field [0001] The present invention relates to copper-containing mixed transition metal thiophosphites Cu x m y P z S 3 (M=Mn, Fe, Ni, Cd) and its preparation method and use. Background technique [0002] Transition metal thiophosphite, as a class of two-dimensional layered materials, exhibits many special physical and chemical properties different from three-dimensional materials, such as strong electrical anisotropy and two-dimensional magnetic anisotropy, etc. These properties originate from Because of their two-dimensional layered structural characteristics; and some intercalation (intercalation) compounds formed based on this structural characteristic exhibit different properties from pure transition metal thiophosphites in terms of electricity, magnetism, light and catalysis. The excellent properties make it a better idea and method for designing and synthesizing molecular-based opto-electromagnetic materials. [0003] For a long time, the preparation of ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B25/14
Inventor 陈兴国秦金贵杨楚罗
Owner WUHAN UNIV
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