Biuret compounds for rheology control
A compound, biuret technology, applied in the field of biuret compounds for rheological control
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0065] In a 1-liter 3-neck flask equipped with a stirrer, reflux condenser and thermometer, 195.0 g (0.5 mol) of hexamethylene diisocyanate uretdione (Desmodur(R) N3400 from Bayer, NCO content=21.5%) was added at room temperature and 138.2 g (1.0 mol) ethylene glycol monophenyl ether, and this initial charge was heated to 70°C. The reaction was carried out until the NCO content was less than 0.1%. Then, the reaction mixture was cooled to 50°C.
[0066] Table 1:
[0067] Example
uretdione
Amine / alcohol component
2
hexamethylene diisocyanate uretdione
Decanol
3
hexamethylene diisocyanate uretdione
4
hexamethylene diisocyanate uretdione
Polyglycol M 350
5
hexamethylene diisocyanate uretdione
6
hexamethylene diisocyanate uretdione
Tridecylamine
7
hexamethylene diisocyanate uretdione
Jeffamine® M 600
8
hexamethylene diisocyan...
Embodiment 10
[0074] In a 1-liter 3-neck flask equipped with a stirrer, a water separator and a thermometer, 227.8 g (0.4 mol) of the dimer acid Pripol was added sequentially TM 1009 (hydrogenated dimerized fatty acid, Uniqema, trimer acid up to 1%), 69.6 g (0.6 mol) hexamethylene diamine and 152.1 g Exxsol D40 (dearomatized hydrocarbon, ExxonMobil Chemical), the original The addition was slowly heated to 170°C. The water slowly released during the reaction is azeotropically separated by a water separator. The condensation product has an amine number of 51. Then, 57.6 g (0.2 mol) of tall oil fatty acid (monocarboxylic acid mixture containing high content of oleic and linoleic acids and about 2% of resin acid (abietic acid), Arizona Chemical GmbH) was added and azeotroped through a water separator The water released during the reaction is separated off. The condensation product had an amine number of 22.7. Then, the reaction mixture was cooled to 50°C.
[0075] Table 2:
[0076] ...
Embodiment 20
[0088] In a 1-liter 3-necked flask equipped with a stirrer, reflux condenser and thermometer, 66.6 g (0.1 mol) of the adduct from Example 1 and 247.1 g (0.1 mol; number of amines = 22.7) from the adduct were sequentially added at room temperature The condensation product of Example 10, the initial charge was heated to 85°C. The reaction mixture was stirred until the amine number was less than one. The product was then diluted with isobutanol to 30% solids.
[0089] table 3:
[0090] Example
Component A
Component B
21
Example 2
Example 19
22
Example 4
Example 11
23
Example 7
Example 15
24
Example 8
Example 13
25
Example 9
Example 14
[0091] Performance results:
[0092] White paint formulation: Worléekyd S 365 white paint, 64% binder, 20% TiO 2
[0093] Worléekyd S 365 70% in K 030 34.4
[0094] Disperbyk(R) 110 0.6
[0095] RKB-2(TiO 2 ) 20.0
[0096...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More