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Hard coating film for forming tool and forming tool

一种硬质皮膜、被覆构件的技术,应用在溅射镀覆、运输和包装、离子注入镀覆等方向,能够解决长期耐久性差、耐烧结性差、弹性和塑性变形举动差异等问题,达到耐烧结性优异、耐久性提高的效果

Active Publication Date: 2008-07-23
KOBE STEEL LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The composite nitrides containing more than two kinds of Cr, Al, Ti, and V disclosed in the above-mentioned JP-A-2000-144376 have high hardness, although they are wear-resistant Excellent wear resistance, but insufficient sintering resistance, and cannot withstand use in severe environments such as metal plastic processing under high surface pressure
Nitrides, carbides, and carbonitrides of one or more of Ti, V, Al, Cr, and Si disclosed in JP-A-2002-307128 also have high hardness, but have poor sintering resistance
In order to improve the seizing resistance, as disclosed in JP-A-2002-307129 and JP-A-2000-1768, when the sulfide is formed, the sulfide is soft, and although it has excellent sliding properties at the beginning of use, it will deteriorate with use. It gradually disappears over time, and there are problems in long-term durability
In addition, Japanese Patent Laid-Open No. 2000-1768 proposes a film with excellent sliding properties consisting of (XC, M1-C) (B aCbN1-a-b) [X: 1 or more of 4a, 5a, 6a, Al, Si, Fe, Co, Ni, M : one or more of V, Mo, and W], but similar to the case of the above-mentioned sulfide, although it has excellent initial sliding properties, it has poor long-term durability
In addition, another problem is that if high-hardness nitrides, carbides, and carbonitrides selected from one or more of Ti, V, Al, Cr, and Si are directly formed on an iron-based base material with low hardness, then Delamination is prone to occur due to differences in its elastic and plastic deformation behavior from the substrate

Method used

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  • Hard coating film for forming tool and forming tool
  • Hard coating film for forming tool and forming tool

Examples

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example 1

[0072] Films having the compositions shown in Tables 1 and 2 were formed using a film forming apparatus ( FIG. 1 ) having a plurality of arc evaporation sources. In this case, as the base material, when forming a film for investigation of film composition, hardness, and crystal structure, use a mirror-polished cemented carbide substrate, and when forming a film for sliding tests at high temperatures, use SKD11 Substrate (hardness HRC60). When any film is formed, the substrate is introduced into the chamber of the film forming device, and the chamber is vacuumed (exhausted to 1×10 -3 Pa or less), the substrate is heated to about 400° C., and then sputter coating is performed using Ar ions. Thereafter, when using an arc evaporation source to form a film, use a target of 100 mm, an arc current of 150 A, and a total pressure of 4 Pa ​​in N 2 Atmosphere or N 2 +CH 4 Film formation is carried out in the mixed gas.

[0073] At the time of film formation, first use a target havi...

example 2

[0086] Films having the compositions shown in Table 3 were produced using a film forming apparatus ( FIG. 1 ) having a plurality of arc evaporation sources. At this time, when forming a film for investigating the composition, hardness, and crystal structure of the film, use a mirror-polished cemented carbide substrate as the substrate, and when forming a film for investigating the adhesion of the film , using SKD11 substrate (hardness HRC 60). When any film is formed, the substrate is introduced into the chamber of the film forming device, and the chamber is vacuumed (exhausted to 1×10 -3 Pa or less), the substrate is heated to about 400° C., and then sputter coating is performed using Ar ions. Thereafter, when using an arc evaporation source to form a film, use a target of 100 mm, an arc current of 150 A, and a total pressure of 4 Pa ​​in N 2 Atmosphere or N 2 +CH 4 Film formation is carried out in the mixed gas.

[0087] At the time of film formation, first, the film l...

example 3

[0096] Films having the compositions shown in Table 4 were produced using a film forming apparatus ( FIG. 1 ) having a plurality of arc evaporation sources. In this case, as the substrate, when forming a film for investigation of the composition, hardness, and crystal structure of the film, use a mirror-polished cemented carbide substrate, and when forming a film for a sliding test at a high temperature, use Various metal materials shown in Table 6. When any film is formed, the substrate is introduced into the chamber of the film forming device, and the chamber is vacuumed (exhausted to 1×10 -3 Pa or less), the substrate is heated to about 400° C., and then sputter coating is performed using Ar ions. Thereafter, when using an arc evaporation source to form a film, use a target of 100 mm, an arc current of 150 A, and a total pressure of 4 Pa ​​in N 2 Atmosphere or N 2 +CH 4 Film formation is carried out in the mixed gas.

[0097] At the time of film formation, first, the ...

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Abstract

A hard coating film excellent in wear resistance and seizure resistance for coating a forming tool of a Cr-containing iron-base alloy includes a first coating layer A of a thickness between 1 and 10 mum formed on the forming tool and a second coating layer B of a thickness between 2 and 10 mum overlying the coating layer A. The first coating layer A is a film of Cr1-xMx(BaCbN1-a-b) meeting conditions expressed by expressions: 0<=x<=0.7, 0<=a<=0.2 and 0<=b<=0.5, where M is at least one element among W, V, Mo, Nb, Ti and Al, x is atomic ratio of M, a is atomic ratio of B and b is atomic ratio of C, and the second coating layer B is a film of Ti1-X-Y-ZCrXAlYLZ(BBCAN1-A-B) meeting conditions expressed by expressions: 0<=1-X-Y-Z<=0.5, 0<X<=0.5, 0.4<=Y<=0.7, 0<=Z<=0.15, 0<=A<=0.5, and 0<=B<=0.2, where L is at least either of Si and Y, X is atomic ratio of Cr, Y is atomic ratio of Al, Z is atomic ratio of L, A is atomic ratio of C and B is atomic ratio of B.

Description

technical field [0001] The technical field to which the present invention belongs relates to a hard-coated member for a molding tool and a molding tool, and particularly relates to a hard-coated member for a molding tool and a molding tool that are excellent in wear resistance. Background technique [0002] Conventionally, tools for metal processing such as dies have been nitrided to improve wear resistance and seizing resistance. In recent years, studies have been conducted to replace nitriding treatment by improving wear resistance and seizing resistance by vapor coating such as PVD. For example, Japanese Unexamined Patent Publication No. 2000-144376 discloses that sliding properties are improved by forming a composite nitride containing two or more types of Cr, Al, Ti, and V. In JP-A-2002-307128 and JP-A-2002-307129, a kind of nitride, carbide, and carbonitride forming Ti, V, Al, Cr, and Si are disclosed, or in A surface-coated metal mold having excellent wear resistanc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/04B32B9/00B32B33/00C23C14/06
CPCC23C14/024C23C28/347C23C28/34C23C14/0641C23C28/00C23C28/321C23C28/36B32B15/013C23C28/324C23C14/0664C23C30/005C23C28/044C23C28/042C23C28/42Y10T428/24975Y10T428/265Y10T428/24967C23C10/00
Inventor 山本兼司
Owner KOBE STEEL LTD