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Thick seawater comprehensive utilization technique after seawater desalination

A technology of concentrated seawater and process, applied in the directions of magnesium hydroxide, bromine/hydrogen bromide, alkali metal chlorides, etc., can solve the problems such as the inability to remove the negative impact of salt production, and achieve the reduction of the amount of bittern and the increase of the concentration of bittern , the effect of improving yield and quality

Inactive Publication Date: 2008-08-06
TIANJIN CHANGLU HAIJING GRP CO LTD
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Problems solved by technology

Using concentrated seawater produced by seawater desalination to make salt can increase the yield of sea salt, but the negative impact of the presence of impurity ions on salt production still cannot be removed

Method used

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  • Thick seawater comprehensive utilization technique after seawater desalination

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Embodiment Construction

[0013] The comprehensive utilization process of desalinated concentrated seawater of the present invention will be described in conjunction with the accompanying drawings and embodiments.

[0014] The invention belongs to a new salinization co-production process, and its basic principle is to use concentrated seawater with 6-8°Bé after seawater desalination as raw material, go through the processes of extracting potassium, magnesium, and bromine, and then mix a small amount of ammonia distillation waste liquid of the same concentration , so that calcium sulfate dihydrate is basically precipitated to obtain "salt gypsum" products, and a large amount of sulfate ions in brine are precipitated, and this brine is used to produce solar salt or liquid salt after further refining. This process can be applied to the comprehensive utilization industry of producing sun-dried industrial salt and concentrated seawater discharged after seawater desalination with seawater and underground brin...

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Abstract

The invention provides a process for comprehensively utilizing desalinated seawater after desalination, including the following steps: the desalinated seawater is collected and potassium is extracted; magnesium is extracted; evaporation concentration is carried out and bromine is extracted; marine gypsum is extracted; salt is made with the desalinated seawater; the desalinated seawater is refined to produce liquid salt. The steps for extracting the potassium, magnesium and bromine of the invention can be inter-modulated. The process has the advantages that: Ca<2+> in saturated brine treated by the process is reduced by 85.21-94.29 percent, Mg<+2> is reduced by 51.22-63.98 percent, SO4<2-> is reduced by 85.57-93.82 percent, Br<-> is reduced by 75 percent, k<+> is reduced by 70 percent, Na<+> is increased by 3.06-5.86 percent and Cl<-> is increased by 7.96-9.38 percent. As ingredient of the brine changes, impendence of the brine evaporation is reduced; yield and quality of the sea salt are improved. The process for producing solar salt can not only effectively utilize chemical resource in the desalinated seawater but also greatly improve the yield and quality of the sea salt product. Bittern quantity of the brine is greatly reduced; if the produced saturated brine is refined, the liquid salt can be produced to directly supply an alkali plant for sintering the alkali.

Description

technical field [0001] The invention relates to a salt-making process and a salinization process, in particular to a process for comprehensive utilization of concentrated seawater after desalination, which can be applied to the comprehensive utilization of concentrated seawater produced after seawater and underground brine are used as raw materials to produce sun-dried industrial salt and the concentrated seawater discharged after seawater desalination . Background technique [0002] In the current production of sea salt, natural seawater is used as raw material, which is gradually concentrated to saturated brine by the action of solar and wind energy, and then continues to evaporate to precipitate sodium chloride crystals. Potassium, calcium, magnesium and sulfate ions in seawater are impurity ions in the production of sea salt, which will not only increase the viscosity and evaporation resistance of brine, and reduce the production of sea salt; Crystal surface, reducing s...

Claims

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Application Information

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IPC IPC(8): C01D3/06C01F5/14C01B7/09C01F11/46
Inventor 张德强魏炳举李萌乔宝栋刘素芹王丹翟拥军陈向峰田凤麟张金娜张冬升
Owner TIANJIN CHANGLU HAIJING GRP CO LTD
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