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Wolfram carbine particle iron based composite material produced with tungsten filament in situ and method of producing the same

A technology of iron-based composite materials and tungsten carbide particles, which is applied in the field of wear-resistant parts

Inactive Publication Date: 2010-12-15
XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a tungsten wire in-situ generation of tungsten carbide (WC) particle iron-based composite material, the composite material tungsten carbide particles and matrix The iron interface is formed by reaction, there is no pollution problem, and a good combination of the composite material and the matrix can be achieved

Method used

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  • Wolfram carbine particle iron based composite material produced with tungsten filament in situ and method of producing the same
  • Wolfram carbine particle iron based composite material produced with tungsten filament in situ and method of producing the same

Examples

Experimental program
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Effect test

Embodiment 1

[0024] In-situ generation of tungsten wire with 3 layers of tungsten carbide particles reinforced gray cast iron matrix (with a carbon equivalent of 3.5%) composite material

[0025] Step 1: Superimpose 3 layers of tungsten wire mesh, press it tightly, and place it on the bottom of the graphite crucible (4), then place the graphite crucible (4) in a resistance furnace to preheat to 400°C. Such as figure 1 shown.

[0026] Step 2: pour the gray cast iron into the graphite crucible (4) at 1280°C (when the carbon equivalent is 3.5%, the melting point is about 1220°C), and then keep it warm in a resistance furnace at 1150°C for 6 minutes, Then cool down to 800°C at a rate of 15°C / min, take it out and cool it down to room temperature naturally.

[0027] The third step: take it out from the graphite crucible (4) to obtain the composite material, the composite layer is a cluster of tungsten carbide (1) particles evenly embedded in the matrix (3), as figure 2 shown.

[0028] The ...

Embodiment 2

[0030] Other conditions are the same as in Example 1. After being kept warm in the resistance furnace at 1147°C for 6min in the second step, the temperature is lowered to 800°C at a rate of 15°C / min, and when it is taken out and naturally cooled to room temperature, its tungsten carbide (1) The generation rate R is: 16.13%. (Theoretical explanation is as follows: when the temperature drops to 1147°C, due to the large degree of undercooling, graphite eutectic and cementite eutectic appear at the same time, resulting in the reduction of the formed graphite phase, thereby reducing the amount of tungsten carbide produced).

Embodiment 3

[0032] Other conditions are the same as in Example 1. After being kept warm in the resistance furnace at 1153°C for 6min in the second step, the temperature is lowered to 800°C at a rate of 15°C / min, and when it is taken out and naturally cooled to room temperature, its tungsten carbide (1) The spawn rate R is: 18.10%. (Theoretical explanation is as follows: when the temperature reaches 1153, the graphite eutectic begins to form, that is, there are not many graphite phases formed; moreover, the reaction between iron and tungsten is intensified, which reduces the amount of tungsten carbide produced)).

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Abstract

The invention discloses a tungsten carbide particle of iron matrix composite, which is made by in situ formation. The invention comprises a tungsten carbide particle produced, a tungsten wire which not completely react and a gray cast-iron. The tungsten carbide particle of iron matrix composite is characterized in that the tungsten carbide particle produced centers around the tungsten wire of notcompletely reacting, distributes around the tungsten wire and embeds in matrix; the composite layer of the tungsten carbide particle is formed by reaction of tungsten screen and graphite type carbon in the iron matrix. The invention also discloses a preparation method of the tungsten carbide particle of iron matrix composite which is made by in situ formation. The interface between the tungsten carbide particle of composite material and the iron matrix is formed by reaction, thereby being without the environmental pollution problem and achieving the good combination of the composite material and the matrix.

Description

Technical field: [0001] The invention relates to an iron-based composite material of tungsten carbide (WC) particles generated in situ by a tungsten wire. The composite material is applicable to wear-resistant parts in metallurgy, mining, building materials and other industries. Background technique: [0002] Tungsten carbide particles reinforced iron-based composite materials have high hardness, high flexural strength and excellent fracture toughness, so they are widely used in cutting metallurgy, mining, building materials, etc. During preparation, tungsten carbide particles are usually added to the matrix, which is called the method of adding a reinforcing phase. The disadvantages of the method of adding a reinforcing phase are (1) the contamination of the interface between the particles and the matrix and the generation of attachments will reduce the binding force between the matrix and the reinforcing particles; (2) the uniform distribution of the particles in the matr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/00C22C37/00B22D23/04
Inventor 许云华牛立斌
Owner XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY