Heavy oil hydrogenating treatment catalyst and preparation method thereof
A technology of oxidation catalyst and hydrogen chloride, which is applied in the direction of preparation of chloride, physical/chemical process catalyst, chlorine/hydrogen chloride, etc., can solve the problems of catalyst active component loss, complicated preparation process, low catalyst activity, etc., and achieve low loss rate , The preparation method is simple and easy, and the effect of increasing the oxygen concentration
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Embodiment 1
[0019] Use 20mL containing 13.5gCuCl 2 2H 2 O, 5.5gKCl and 17.5gCe(NO 3 ) 3 ·6H 2 The aqueous solution of O, 50g ReY molecular sieve (dry basis, purchased from Wenzhou Huahua Group Company, the same below), 0.5g field turnip powder (80-100 mesh, purchased from Jiangsu Huahua Chemical Company, the same below), and fully After stirring for 30 minutes, a viscous powder with a humidity of 60% was obtained, which was molded in an extruder to obtain a hydrogen chloride oxidation catalyst with a particle size of 3 mm. Hydrogen chloride is derived from the chlorinated by-products on the toluene ring. After adsorption and purification by alumina, the -1 , the reaction temperature is 360°C, V(HCl) / V(O 2 )=1.5 under the condition of reaction, reaction product is absorbed with excessive KI solution, obtains the hydrochloric acid solution of iodine, respectively with 0.1mol L -1 Na 2 S 2 o 3 Iodine generated by titration of standard solution, with 0.1mol L -1 NaOH standard soluti...
Embodiment 2
[0021] Use 20mL containing 13.5gCuCl 2 2H 2 The aqueous solution of O and 5.5gKCl and 50gReY molecular sieve (dry basis), 0.5g kale powder, obtain the viscous powder that humidity is 60% after fully stirring 30min in the mortar, shape in extruder, obtain particle diameter and be 3mm hydrogen chloride Oxidation catalyst is reacted under the reaction conditions of example 1, and the reaction result after 6 hours is shown in Table 1.
Embodiment 5
[0029] With 20mL containing 14.6gCuCl 2 2H2 O, 5.5gKCl and 14.8gCe(NO 3 ) 3 ·6H 2 The aqueous solution of O and 50gReY molecular sieve (dry base), 0.5g turmeric powder, obtain the viscous powder that humidity is 60% after fully stirring 30min in mortar, mold in extruder, obtain particle diameter and be that 3mm hydrogen chloride oxidation catalyst, The reaction was carried out under the reaction conditions of Example 1, and the conversion rate of hydrogen chloride was 60% after 6 hours.
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