Electrolyte for the galvanic deposition of aluminium from aprotic solvents in a plating barrel

An electrolyte and aprotic technology, which is applied in the fields of compounds containing group 3/13 elements of the periodic table, chemical instruments and methods, organic chemistry, etc., can solve problems such as deficiencies, and achieve high plating ability and uniform corrosion resistance.

Inactive Publication Date: 2009-11-04
ALUMINAL OBERFLACHENTECHN
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This conductivity is insufficie

Method used

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  • Electrolyte for the galvanic deposition of aluminium from aprotic solvents in a plating barrel
  • Electrolyte for the galvanic deposition of aluminium from aprotic solvents in a plating barrel

Examples

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[0053] Example

[0054] 1. Preparation of electrolyte

[0055] Tetraethylammonium chloride, which can be purchased as a monohydrate, is dried under vacuum. One mole of dried tetraethylammonium chloride was mixed with toluene to obtain a suspension. During cooling, 2 moles (used as pure substance or as a toluene solution) of triethylaluminum are added dropwise to the suspension. The reaction mixture was stirred. Get N(C 2 H 5 ) 4 Cl·2Al(C 2 H 5 ) 3 ·2 A clear solution of toluene. With respect to the usage amount of tetraethylammonium chloride, 2 moles of toluene was used as a solvent. The resulting product is used as an electrolyte.

[0056] 2. The conductivity of the electrolyte of the present invention is compared to the conductivity of the electrolyte of the prior art

[0057] Adequate conductivity of the electrolyte is a basic requirement for adequate coating, especially for small parts in the coating drum. The conductivity of the electrolyte of the present invention is signifi...

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Abstract

The invention relates to an electrolyte for the galvanic deposition of al uminium from aprotic solvents, said electrolyte containing a compound of for mula N(R1)4X.(m-n-o)AI (C2H5)3-n AIR2 3-o AIR3 3 (I), wherein R1 is a C1 to C4 alkyl group, X is equal to F, Cl or Br, m is equal to between 1 and 3, pr eferably between 1.7 and 2.3, n is equal to between 0.0 and 1.5, preferably 0.0 and 0.6, o is equal to between 0.0 and 1.5, preferably between 0.0 and 0 .6, and R2 and R3 are a C1 or C3 to C6 alkyl group, R2 differing from R3in a n organic solvent. The invention also relates to a method for producing the electrolyte, a coating method and the coated material parts.

Description

technical field [0001] The subject of the present invention is an electrolyte for the electrodeposition of aluminum from aprotic solvents, preferably for roller coating of the material. Further subjects of the invention are the method for producing the electrolyte, the use of the electrolyte, the coating method and the components coated with the method. Background technique [0002] It is known that the electrodeposition of aluminum is only possible from non-aqueous electrolytes, since this metal has a very low electrode potential. [0003] In principle, electrodeposition of aluminum is carried out in non-aqueous systems by using electrolytes containing organoalkylaluminum complexes dissolved in organic aprotic solvents. Coating is carried out in such a way that the material to be coated operates as a cathode in the electrolyte solution. In addition, the electrolyte solution contains an aluminum anode to provide the aluminum necessary for coating. When an electric current...

Claims

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Application Information

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IPC IPC(8): C25D3/44C07F5/06
CPCC07F5/062C25D3/44
Inventor H·德弗里斯M·黑特尔
Owner ALUMINAL OBERFLACHENTECHN
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