The application provides a brightener, a preparation method and application thereof. The brightener has a structure as shown in formula 1, wherein R is any one of CH3-(CH2) x -, Ph-(CH2) y - or an azacyclic group, x is 2-5, and y is 0-4. The brightener is connected with a functional group having strong polarity, has good inhibition effect on
copper, and has a capturing
cuprous ion at the other end of the structure, accelerates
copper deposition, has certain leveling performance, can form
leveling effect on the surface
copper high potential, forms acceleration effect on the low point position in the hole, and can effectively improve the deep plating capacity of the acid
copper plating solution, and the deep plating capacity can reach 79-85%.