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Method for producing SiC single crystal

一种制造方法、单晶的技术,应用在单晶生长、单晶生长、化学仪器和方法等方向,能够解决未实现高的晶体生长速度、未充分满足、高生长面平滑度等问题

Inactive Publication Date: 2012-05-02
TOYOTA JIDOSHA KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, none of these techniques adequately meets both requirements
[0008] Therefore, none of the above-mentioned technologies in the related art has achieved a high crystal growth rate and a high growth surface smoothness.

Method used

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  • Method for producing SiC single crystal
  • Method for producing SiC single crystal
  • Method for producing SiC single crystal

Examples

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Embodiment Construction

[0014] Examples of the present invention are described below. In this example, a SiC single crystal was fabricated using a Si-Ti-M-C quaternary solution ("M" is Sn or Ge) by adding Ti and Sn or Ge to a Si-C2 binary solution As a result, both high growth surface smoothness and high growth speed are achieved. The addition amounts of Ti, Sn and Ge are as follows. Note that in this specification, the amount of each additive in the Si melt is expressed relative to the amount of the entire Si melt.

[0015] Ti increases the amount of C dissolved into the Si melt from the graphite crucible, thereby accelerating the growth of a single crystal. In order to obtain this effect, the addition amount of Ti needs to be at least 5 atomic % with respect to the amount of the whole Si melt. However, adding too much Ti to the Si melt may cause the resulting single crystal to have an uneven growth face. Therefore, the amount of Ti added is set to 30 atomic % or less. That is, if more than 30 ...

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Abstract

5 to 30 at% of Ti and 1 to 20 at% of Sn or 1 to 30 at% of Ge are added to an Si melt, and SiC single crystal are grown from SiC seed crystal by holding the SiC seed crystal immediately beneath the surface of the Si melt in a graphite crucible while maintaining temperature gradient descending from the inner side of the Si melt to the surface of the melt.

Description

technical field [0001] The present invention relates to a method for manufacturing SiC single crystals using a solution. Background technique [0002] The energy bandgap of silicon carbide (SiC) is larger than that of silicon (Si). Therefore, various methods have been proposed to produce high-quality SiC single crystals suitable as semiconductor materials. These methods are mainly classified into sublimation methods and solution methods. The solution method has drawn more attention from those skilled in the art due to its relatively high polytype controllability and effective reduction of microtubules. [0003] In a typical solution method, the temperature gradient of the Si melt in the graphite crucible is maintained such that the temperature drops from the inside of the Si melt toward its surface. Carbon (C) in the high temperature zone on the lower side of the graphite crucible dissolves into the Si melt, and then it rises mainly through the convection of the Si melt t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C30B29/36C30B9/00
CPCC30B29/36C30B9/00
Inventor 坂元秀光
Owner TOYOTA JIDOSHA KK
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