Low phenyl siloxane rubber-based wide temperature-range and high-damping material

A technology of low phenyl silicone rubber and high damping, which is applied in the field of damping rubber materials and additional damping treatment materials for structures, wide temperature and high damping materials, and can solve the problems of not meeting the requirements of use, relatively large gaps, and low tensile strength , to achieve the effects of good damping, wide temperature range and good mechanical properties

Active Publication Date: 2011-02-02
AEROSPACE RES INST OF MATERIAL & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The applicable temperature of existing damping materials in China is generally around -30~+100℃, the damping factor β is only up to about 0.2, the tensile strength is low, and either the applicable temperature range is narrow or the damping factor is low, which cannot reach a wide temperature range. It has both good damping and vibration isolation performance and good mechanical properties. Compared with the performance of foreign damping materials, there is a big gap, and it can no longer meet the requirements of complex and harsh environments. Therefore, it is urgent to improve the existing materials and develop the use of Wider temperature range (-50~+150℃), higher damping factor (damping coefficient β max ≥0.2) damping material to meet the needs of various equipment and instruments

Method used

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  • Low phenyl siloxane rubber-based wide temperature-range and high-damping material
  • Low phenyl siloxane rubber-based wide temperature-range and high-damping material
  • Low phenyl siloxane rubber-based wide temperature-range and high-damping material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Damping material ratio (mass percentage):

[0038] Low phenyl silicone rubber 50.8%,

[0039] Vinyl silicone oil 2.5%,

[0040] Silica 45.6%,

[0041] Peroxide vulcanizing agent 0.8%,

[0042] Pigment 0.3%.

[0043] Preparation Process:

[0044] Add vinyl silicone oil to the low phenyl silicone rubber, then add white carbon black, peroxide vulcanizing agent and pigments in sequence, mix at less than 60℃, vulcanize at 110℃ for 15min after discharging, and then heat up within 1 hour After the temperature reaches 200°C, keep it for 4 hours and then cool to room temperature naturally.

[0045] performance:

[0046] The tensile strength of the damping material of this embodiment is 7.1MPa, the permanent deformation at break is 12%, the elongation at break is 200%, the shear modulus is 13MPa, and the damping factor β is in the temperature range of -50~+150℃ max Is 0.36.

[0047] The damping material obtained by adopting the above formula can be used in a vibration damping environment with ...

Embodiment 2

[0049] Damping material ratio (mass percentage):

[0050] Low phenyl silicone rubber 63.7%,

[0051] Vinyl silicone oil 3.2%,

[0052] White carbon black 31.8%,

[0053] Peroxide vulcanizing agent 1.0%,

[0054] Pigment 0.3%.

[0055] Preparation Process:

[0056] Add vinyl silicone oil to the low phenyl silicone rubber, then add white carbon black, peroxide vulcanizing agent and pigment in sequence, mix at less than 60℃, and vulcanize at 120℃ for 20min after the sheet is discharged, and then within 1 hour Warm up to 200°C, keep it for 4 hours, and then cool to room temperature naturally.

[0057] performance:

[0058] The tensile strength of the damping material of this embodiment is 10MPa, the tear strength is 45kN / m, the permanent deformation at break is 6%, the elongation at break is 939%, and the damping factor β is in the temperature range of -50~+150℃ max Is 0.32. The elastic shear modulus of the damping material is around 2MPa. At this time, the damping material has the highest st...

Embodiment 3

[0060] Damping material ratio (mass percentage):

[0061] Low phenyl silicone rubber 78.7%,

[0062] Vinyl silicone oil 3.9%,

[0063] White carbon black 15.8%,

[0064] Peroxide vulcanizing agent 1.2%,

[0065] Pigment 0.4%.

[0066] Preparation Process:

[0067] Add vinyl silicone oil to the low phenyl silicone rubber, then add white carbon black, peroxide vulcanizing agent and pigment in sequence, mix at less than 60℃, and vulcanize at 130℃ for 25min after discharging, and then within 1 hour Warm up to 200°C, keep it for 4 hours, and then cool to room temperature naturally.

[0068] performance:

[0069] The tensile strength of the damping material of this embodiment is 5.5 MPa, the permanent deformation at break is 25%, the elongation at break is 1310%, the shear modulus is 0.5 MPa, and the damping factor βmax is 0.29 in the temperature range of -50 to +150°C. The elastic shear modulus of the damping material is below 0.8Mpa, which can be used in the environment with low resonant freq...

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Abstract

The invention discloses a low phenyl siloxane rubber-based wide temperature-range and high-damping material, which comprises following components in percentage by mass: 50.8 to 78.7 percent of low phenyl siloxane rubber, 2.5 to 3.9 percent of vinyl silicone oil, 15.8 to 45.6 percent of white carbon black, 0.8 to 1.2 percent of peroxide vulcanizer and 0.3 to 0.4 percent of pigment. The damping material is improved on the conventional materials and has high damping, vibration-insulation and buffering properties and a high mechanical property in a relatively wide temperature range; the material can meet requirements for use under the following conditions: the stretching strength is more than or equal to 5 MPa, the elongation rate at rupture is more than or equal to 200 percent, the permanent deformation rate at rupture is less than or equal to 25 percent, the damping coefficient beta max is more than or equal to 0.2 and the temperature is 50 DEG C below zero to 150 DEG C. The low phenyl siloxane rubber-based wide temperature-range and high-damping material has be been applied to a plurality of devices or instruments, achieves considerable vibration insulation and buffering effects and therefore can be applied to instruments and electronic systems of airplanes, ships and vehicles for vibration control and noise control and has a promising application prospect.

Description

Technical field [0001] The invention relates to a wide temperature (within a temperature range of -50 to +150°C) high damping (damping coefficient β) max ≥0.2) material, especially related to a wide temperature and high damping material based on low phenyl silicone rubber (phenyl content less than 7%), which belongs to the technical field of damping material formulation design, and is mainly used as a damping rubber for isolator / shock absorber Additional damping treatment materials for materials and structures. Background technique [0002] Damping vibration isolation technology developed based on viscoelastic damping materials is an effective way to control vibration, shock and noise, and an effective means to improve the mechanical environment of structures and equipment, especially for broadband random vibration and shock problems of high-precision equipment More irreplaceable, viscoelastic damping materials and their products have been widely used in the vibration and noise c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08K3/36C08L83/07C08K13/02
Inventor 黄加才王立峰李诗成赵云峰游少雄李晓颜赵鸿敬林树凯张风生付万军李杰
Owner AEROSPACE RES INST OF MATERIAL & PROCESSING TECH
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