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High phenyl siloxane rubber-based high-intensity, wide-temperature range and high-damping material

A silicone rubber, high phenyl technology, applied in the field of high-strength, wide-temperature and high-damping materials, damping rubber materials and additional damping treatment materials for structures, can solve the problems of inability to meet use requirements, low tensile strength, low damping factor, etc. Achieve significant vibration isolation and buffer effect, good mechanical properties, and the effect of less volatile matter

Active Publication Date: 2012-05-16
AEROSPACE RES INST OF MATERIAL & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The applicable temperature of existing domestic damping materials is generally around -30~+100℃, the damping factor β is only up to about 0.2, the tensile strength is low, and either the applicable temperature range is narrow or the damping factor is low, which cannot reach a wide temperature range. It has both good damping and vibration isolation performance and good mechanical properties. Compared with the performance of foreign damping materials, there is a big gap, and it can no longer meet the requirements of complex and harsh environments. Therefore, it is urgent to improve the existing materials and develop the use of Wider temperature range (-50~+150℃), higher damping factor (damping coefficient β max ≥0.2), higher strength (tensile strength ≥7MPa) damping material to meet the needs of various equipment and instruments

Method used

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  • High phenyl siloxane rubber-based high-intensity, wide-temperature range and high-damping material
  • High phenyl siloxane rubber-based high-intensity, wide-temperature range and high-damping material
  • High phenyl siloxane rubber-based high-intensity, wide-temperature range and high-damping material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Damping material ratio (mass percentage):

[0038] High phenyl silicone rubber 87.7%,

[0039] Peroxide vulcanizing agent 1.8%,

[0040] Mica flakes 8.7%,

[0041] Acrylic damping agent 1.8%.

[0042] Preparation Process:

[0043] Add the peroxide vulcanizing agent into the high phenyl silicone rubber, then add mica flakes and acrylic damping agent, knead at 55°C, vulcanize at 165°C for 15 minutes after the sheet is released, and then heat up to 200°C within 40 minutes , keep warm for 4h and then cool down to room temperature naturally.

[0044] performance:

[0045] The tensile strength of the damping material in this example is 7.5MPa, the tear strength is 28.5MPa, the permanent deformation at break is 14%, and the damping factor β in the temperature range of -50~+150℃ max It is 0.41, and the shear modulus is greater than 2.4MPa.

Embodiment 2

[0047] Damping material ratio (mass percentage):

[0048] High phenyl silicone rubber 91.8%,

[0049] Peroxide vulcanizing agent 1.8%,

[0050] Mica flakes 4.7%,

[0051] Acrylic damping agent 1.7%.

[0052] Preparation Process:

[0053] Add the peroxide vulcanizing agent into the high phenyl silicone rubber, then add the mica sheet and damping agent, knead at 60°C, vulcanize at 170°C for 20min after the sheet is released, then raise the temperature to 200°C within 50min, and keep it warm for 4h Then cool down to room temperature naturally.

[0054] performance:

[0055] The tensile strength of the damping material in this example is 8.9MPa, the tear strength is 31.6KN / m, the permanent deformation at break is 16%, and the damping factor β in the temperature range of -50~+150℃ max It is 0.49, and the shear modulus is greater than 2MPa.

Embodiment 3

[0057] Damping material ratio (mass percentage):

[0058] High phenyl silicone rubber 96.2%,

[0059] Peroxide vulcanizing agent 1.9%,

[0060] Acrylic damping agent 1.9%.

[0061] Preparation Process:

[0062] Add the peroxide vulcanizing agent into the high phenyl silicone rubber, then add the damping agent, knead at 60°C, vulcanize at 175°C for 20 minutes after the tablet is released, then raise the temperature to 200°C within 60 minutes, keep it warm for 4 hours and then naturally Let cool to room temperature.

[0063] performance:

[0064] The tensile strength of the damping material in this example is 7.5MPa, the tear strength is 35KN / m, the permanent deformation at break is 22%, and the damping factor β in the temperature range of -50~+150℃ max is 0.5, and the shear modulus is greater than 2MPa.

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Abstract

The invention relates to a high phenyl siloxane rubber-based high-intensity, wide-temperature range and high-damping material. The material comprises the following components in percentage by mass: 87.7 to 96.2 percent of high phenyl siloxane rubber, 1.8 to 1.9 percent of peroxide vulcanizing agent, 0 to 8.7 percent of mica sheet, 0 to 1.9 percent of acrylic ester damping agent and 0 to 8.9 percent of methyl methacrylate copolymer. The damping material is used for modifying the conventional material, so that the modified conventional material has high damping, vibration isolating and buffering performance as well as high mechanical property in a relatively wide temperature range; the material can meet the requirements of the tensile strength of more than or equal to 7 MPa, the elongation at rupture of more than or equal to 300 percent, the tearing strength of more than or equal to 20 kN / m, the damping coefficient beta max of more than or equal to 0.2 and the tearing permanent deformation of less than or equal to 25 percent and meets using requirements at the temperature of between 50 DEG C below zero and 150 DEG C; and volatile substances such as a plasticizer and process oil are not added in the formula of the material, so that the number of volatile matters in vacuum atmosphere is small and the pollution of the volatile matters on certain equipment on which the material is used is avoided.

Description

technical field [0001] The invention relates to a high-strength (tensile strength ≥ 7MPa) wide temperature (in the temperature range of -50 to +150 ℃) high damping (damping coefficient β max ≥0.2) materials, especially a high-strength, wide-temperature, and high-damping material based on high-phenyl silicone rubber (the phenyl content is greater than 15%, by mass percentage), belongs to the technical field of damping material formulation design, and is mainly used for vibration isolation / damping The damping rubber material of the device and the additional damping treatment material of the structure. Background technique [0002] The damping vibration isolation technology developed based on the viscoelastic damping material is an effective way to control vibration, impact and noise, and an effective means to improve the mechanical environment of structures and equipment, especially for broadband random vibration and impact problems of high-precision equipment Even more irrep...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L83/04C08L33/12C08K3/34
Inventor 黄加才王立峰李诗成赵云峰游少雄李晓颜赵鸿敬林树凯张风生付万军李杰
Owner AEROSPACE RES INST OF MATERIAL & PROCESSING TECH
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