Liquid crystal aligning agent, liquid crystal aligning film, liquid crystal display element, compound and manufacture method of the compound
A liquid crystal aligning agent and compound technology, applied in chemical instruments and methods, liquid crystal materials, organic chemistry, etc., can solve the problems of increased residual DC voltage value and long driving time, and achieve excellent weather resistance and good liquid crystal alignment performance. and the effect of electrical properties
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[0195] Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not interpreted limitedly by the description of this Example.
[0196]
Synthetic example 1
[0198] With 98g (0.50 mole) 1,2,3,4-cyclobutanetetracarboxylic dianhydride and 110g (0.50 mole) pyromellitic dianhydride as tetracarboxylic dianhydride, and 200g (1.0 mole) as diamine mol) 4,4'-diaminodiphenylmethane, dissolved in a mixed solvent of 230g N-methyl-2-pyrrolidone and 2100g γ-butyrolactone, reacted for 3 hours at 40°C, and then added 1,350 g of γ-butyrolactone was used to obtain a solution containing 10 mass % of polyamic acid (PA-1). The solution viscosity of this solution is 125mpa.s.
Synthetic example 2
[0200] 200g (1.0 mole) of 1,2,3,4-cyclobutanetetracarboxylic dianhydride as tetracarboxylic dianhydride and 210g (1.0 mole) of diamine as 2,2'-dimethyl-4, 4'-Diaminobiphenyl, dissolved in a mixed solvent of 370g N-methyl-2-pyrrolidone and 3300g γ-butyrolactone, reacted for 3 hours at 40°C to obtain polyamic acid containing 10% by mass (PA-2) solution. The solution viscosity of this solution was 160 mPa·s.
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