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A liquid crystal panel, liquid crystal display technology, applied in the direction of adhesive types, film/sheet adhesives, instruments, etc., can solve problems such as wide molecular weight distribution, achieve excellent reworkability, inhibit whitening, and improve durability sexual effect
Active Publication Date: 2011-04-27
SUMITOMO CHEM CO LTD
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By using such an adhesive layer, although the light leakage is reduced, it is not necessarily sufficient,
Method used
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Embodiment 1～6 and comparative example 1～5
[0291] (a) Preparation of Adhesive Composition
[0292] 0.5 parts of the silane compound (KBM-403) and the crosslinking agent (Coronate L) The respective amounts shown in Table 3 were mixed, and ethyl acetate was further added so that the solid content concentration became 13%, to prepare an adhesive composition.
[0293] (b) Preparation of polarizing plate with adhesive layer
[0294] Using an applicator, each adhesive composition prepared in the above (a) was applied to a polyethylene terephthalate film ( The release-treated surface of "PET 3811" (available from Lintec Co., Ltd., which is called a spacer) was dried at 90° C. for 1 minute to produce a sheet-shaped adhesive layer. Next, one side of a three-layered polarizing plate in which iodine is adsorbed in polyvinyl alcohol and iodine is oriented is interposed between protective films made of cellulose triacetate, and the upper side is laminated with a laminator to obtain The surface (adhesive surface) of the sheet-shape...
Embodiment 7～11 and comparative example 6～9
[0322] (a) Preparation of Adhesive Composition
[0323] 0.5 parts of the above-mentioned silane-based compound (KBM-403), a crosslinking agent (Coronate L ) mixed each amount shown in Table 4, and the amount shown in Table 4 of mixed ionic compounds (wherein, embodiment 7 and comparative example 8 did not use ionic compounds), and then added with a solid content concentration of 13% Ethyl acetate, to prepare the adhesive composition.
[0324] (b) Preparation of polarizing plate with adhesive layer
[0325] Using an applicator, each adhesive composition prepared in the above (a) was applied to a polyethylene terephthalate film ( The release-treated surface of "PET 3811" (available from Lintec Co., Ltd., which is called a spacer) was dried at 90° C. for 1 minute to produce a sheet-shaped adhesive layer. Next, one side of a three-layered polarizing plate in which iodine is adsorbed in polyvinyl alcohol and iodine is oriented is interposed between protective films made of cellu...
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Abstract
The present invention provides a liquid crystal panel which is obtained through: adhibiting a first polarizing sheet (21) to one surface of a liquid crystal unit (10) through a first adhesive layer (31) with a mode that an absorption axis (21A) is parallel with a long edge (10A) of a liquid crystal unit, and adhibiting a second polarizing sheet (22) to the other surface of the liquid crystal unit (10) through a second adhesive layer (32) with a mode that an absorption axis (22A) is orthogonal with the absorption axis (21A) of the first polarizing sheet. At least one layer selected from the adhesive layers (31,32) is composed of the adhesive composition. The adhesive composition comprises 100 weight parts of acrylic resin (A) and 0.01-5 weight parts of crosslinking agent (B), wherein the acrylic resin is obtained through copolymerizing 80-96% by weight of (methyl)alkyl acrylate, 3-15% by weight of aromatic ring monomer and 0.1-15% by weight of polar functional groups and has 1000,000-2000,000 of weight average molecular weight and 3-7 of molecular weight distribution. The gel fractions of the adhesive layers are set to 60-99wt%. According to the liquid crystal panel, two surfaces of the liquid crystal unit are respectively adhibited with a pair of polarizing sheet through the adhesive layer. The liquid crystal panel can restrain white discharge even when size is enlarged.
Description
technical field [0001] The present invention relates to a liquid crystal panel in which a polarizing plate is pasted on both sides of a glass unit for liquid crystal display via an adhesive layer. Background technique [0002] The polarizing plate is mounted on a liquid crystal display device and is widely used. A transparent protective film is laminated on both sides of the polarizing film, an adhesive layer is formed on the surface of at least one protective film, and a release film is pasted on the adhesive layer. status in circulation. Moreover, a retardation film is laminated|stacked on the polarizing plate of the state which attached the protective film to both surfaces of a polarizing film, and the pressure-sensitive adhesive layer / release film is also stuck on this retardation film side. Before bonding to the liquid crystal cell, the release film is peeled off from these polarizers, and the exposed adhesive layer is bonded to the glass cell for liquid crystal displa...
Claims
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