Neodymium iron boron magnet, preparation method and device applying same

A technology of NdFeB and magnets, applied in the direction of magnetic objects, inductance/transformer/magnet manufacturing, magnetic materials, etc., can solve the problems of high price, narrow range, limited storage, etc., and achieve high temperature working stability and extended use Lifetime, Effect of Low Temperature Coefficient

Active Publication Date: 2011-06-22
GRIREM ADVANCED MATERIALS CO LTD
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AI Technical Summary

Problems solved by technology

[0003] For example, adding a certain amount of heavy rare earth elements Tb, Dy and transition metals Cu, Zr, Ga, Al, etc. to the sintered NdFeB master alloy can effectively improve the coercive force of the magnet, especially the addition of heavy rare earth elements Tb and Dy, It can significantly improve the coercive force of the magnet, but Tb and Dy are expensive strategic metals, their reserves are limited, the price is expensive, and it is achieved by sacrificing the remanence and magnetic energy product while bringing about the improvement of the coercive force, so It is necessary for us to explore other substituting elements to improve the coercivity and ensure that other properties do not decrease
Zhongke Sanhuan (application number 200710090597.3) mentioned that the use of Gd can increase the coercive force of the magnet, but its Gd range is narrow. a very important indicator of
Jiangxi Chen Jiuchang only mentioned mixing rare earth metals containing Gd. Although the cost of rare earth raw materials has been reduced, this method can only produce low-grade magnets, and no significant increase in coercive force has been found. Research on other performance indicators of magnets
In a word, the previous research found that Gd was used to improve the coercive force, but it was not found that the compound addition of Co, M1, and M2 through composition adjustment can be used to achieve performance optimization, so that the coercive force can be increased without reducing the remanence and magnetic energy product of the magnet. Not to mention the reversible magnetic induction temperature coefficient α and coercive force temperature coefficient β

Method used

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  • Neodymium iron boron magnet, preparation method and device applying same
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  • Neodymium iron boron magnet, preparation method and device applying same

Examples

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Embodiment 1

[0045] The preparation method of this embodiment is as follows: while adding Gd, we adopt composite addition of Co and M1 (Cu in this embodiment), M2 (0 in this embodiment), and design the magnet Nd by adjusting the appropriate ratio 27 Gd 2 co 0.5 Cu 0.5 Fe bal B 1.2 (Magnet 1), designed two kinds of comparison examples: (1) we have made the magnet that only contains Gd and does not contain M1 (the present embodiment is Cu), Co, and its composition is Nd 27 Gd 2 Fe bal B 1.2 (Magnet 2), as comparison 2, (2) we follow Nd 27 Fe bal B 1.2 (Magnet 3) Composition A magnet that does not contain Gd, Co, M1, and M2 was produced. The processes of the three magnets are the same. The corresponding magnet properties are shown in Table 1. The final oxygen content of the magnet is 2000ppm, and the specific process parameters are: powder particle size 3μm , Orientation magnetic field: 1.2T, isostatic pressure: 100Mpa, sintering temperature: 1070°C for 2 hours, then cool at 1200°C / ...

Embodiment 2

[0049] The preparation method of this embodiment is as follows: we adopt the compound addition of Co and M1 (Ge in this embodiment), M2 (Nb in this embodiment) while adding Gd, and design the magnet Nd by adjusting the appropriate ratio. 30 PR 5 Gd 0.55 Ge 0.1 Nb 0.5 Fe bal B 0.9 (Magnet 1), designed two kinds of comparison examples: (1) we have made the magnet that only contains Gd and does not contain Co, M1 (this embodiment is Ge) and M2 (this embodiment is Nb), and its composition is Nd 35 Gd 0.55 Fe bal B 0.9 (Magnet 2), as comparison 2, (2) we follow Nd 30 PR 5 Fe bal B 0.9 (Magnet 3) Composition A magnet that does not contain Gd, Co, M1, and M2 was produced. The processes of the three magnets are the same. The corresponding magnet properties are shown in Table 2. The final oxygen content of the magnet is 2200ppm, and the specific process parameters are: powder particle size 5μm , Orientation charging magnetic field: 2T, isostatic pressure: 200Mpa, sintering ...

Embodiment 3

[0053] The preparation method of this embodiment is as follows: while adding Gd, we adopt composite addition of Co, M1 (Al in this embodiment), M2 (Zr in this embodiment), and design the magnet Nd by adjusting the appropriate ratio. 22 PR 7 Gd 1.5 co 3.5 Al 0.15 Zr 0.5 Fe bal B 1.0 (Magnet 1), designed two kinds of comparison examples: (1) we have made the magnet that only contains Gd and does not contain Co, M1 (this embodiment is Al), M2 (this embodiment is Zr), and its composition is Nd 29 Gd 1.5 Fe bal B 1.0 (Magnet 2), as comparison 2, (2) we follow Nd 22 PR 7 Fe bal B 1.0 (Magnet 3) Composition A magnet that does not contain Gd, Co, M1, and M2 is produced. The processes of the three magnets are the same. The corresponding magnet properties are shown in Table 3. The final magnet oxygen content is 1200ppm, and its specific process parameters are: powder particle size 3.5 μm, orientation charging magnetic field: 1.5T, isostatic pressure: 150Mpa, sintering tempe...

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Abstract

The invention discloses a neodymium iron boron magnet, a preparation method and a device applying the same, belonging to the field of magnetic materials. The magnet comprises the following components in percentage by weight according to the general formula: 27 to 35 percent of R representing one or two rare-earth elements except Gd, 0.55 to 2 percent of Gd, 0.5 to 3.5 percent of Co, 0.05 to 0.5 percent of M1 representing one transition metal element such as Cu, Al or Ge, 0 to 0.5 percent of M2 being one or two transition metal elements except Co and M1, 0.9 to 1.2 percent of B (namely boron) and the balance of Fe and unavoidable impurities. The neodymium iron boron magnet disclosed by the invention is compounded with Gd, Co, M1 and M2, thus the reversible magnetic induction temperature coefficient alpha and the coercive force temperature coefficient beta are better improved, the coercive force of the magnet is greatly improved while the magnetic energy product and residual magnetism are guaranteed not to reduce, the heavy rare earth element Gd is effectively utilized, and the performance is improved while the manufacturing cost is well saved.

Description

technical field [0001] The invention relates to a neodymium-iron-boron magnet, a preparation method and a device using the magnet, belonging to the field of magnetic materials. The invention is mainly a method for preparing a low-cost magnet with good high-temperature stability by adjusting the element composition and adding low-cost elements Gd and Co, M1, and M2 in combination. Background technique [0002] Neodymium iron boron (NdFeB) permanent magnet has the characteristics of small size, light weight and strong magnetism. It is the magnet with the best performance and price ratio so far, and is known as the king of magnetism in the magnetic field. NdFeB permanent magnet materials are widely used in high-tech fields such as computers, communications, and national defense due to their excellent performance, and new application fields continue to emerge. Its development and application level has become a symbol of a country's national strength and development level. Motor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/057H01F41/02
Inventor 颜世宏闫文龙于敦波李红卫胡权霞李世鹏袁永强
Owner GRIREM ADVANCED MATERIALS CO LTD
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