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Refining method for producing stainless steel by VOD (vacuum oxygen decarburization) blowing CO2

A CO2 and stainless steel technology, applied in the field of out-of-furnace refining, can solve the problems of increased use of reduced alloys, large use of deoxidized alloys, and high dissolved oxygen content, reducing the use of alloys, good promotion and application prospects, and alleviating the greenhouse effect. Effect

Active Publication Date: 2011-08-10
ANGANG STEEL CO LTD
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Problems solved by technology

Originally, this process only blows oxygen at the top, and the chromium in the molten steel is seriously oxidized after the carbon content drops below 0.5%, resulting in an increase in the use of reduced alloys in the later stage.
Secondly, due to the use of oxygen for decarburization, the dissolved oxygen content in the molten steel at the end of refining and the oxidative property in the slag are relatively high, resulting in a large amount of deoxidized alloys and high costs

Method used

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  • Refining method for producing stainless steel by VOD (vacuum oxygen decarburization) blowing CO2

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Embodiment Construction

[0012] In order to achieve the best implementation effect, the following implementation methods are adopted as shown in Table 1. In the embodiment, the pressure of the bottom blowing gas is 0.6 MPa, and the pressure of the top blowing gas is 1.0 MPa. Injection gas concentration: O 2 99.6%, CO 2 99.4% and Ar 99.9%.

[0013] Table 1 Embodiment and effect of the present invention

[0014]

[0015] Using the above embodiment, it can be seen from the comparative examples that, under the condition that the initial condition of molten steel and the intensity of gas supply are basically the same, the final carbon content is basically the same, and the temperature is also basically the same, but the a[o] of molten steel is reduced by 24%, and the slag is oxidized Sex decreased by 11.5%.

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Abstract

The invention discloses a refining method for producing stainless steel by vacuum oxygen decarburization (VOD) blowing CO2. The method is characterized in that CO2 gas is blown into molten steel in a VOD refining process. The method comprises that: the bottom blowing gas is CO2 after the smelted primary molten steel is carried into a VOD, the blowing strength is 0.1 to 0.5Nm<3> / min.t, and then the pure oxygen is blown by adopting a top oxygen lance till the carbon content is less than 0.5 percent, wherein the blowing strength of the O2 is 2.5 to 3.0Nm<3> / min.t; the pure oxygen is blown by adopting the top oxygen lance, wherein the blowing strength of the O2 is 2.0 to 2.3Nm<3> / min.t; when the carbon content is less than 0.1 percent, the mixed gas of the O2 and the CO2 is blown by adopting the top oxygen lance, wherein the blowing strength of the O2 is 2.0 to 2.3Nm<3> / min.t, and the blowing strength of the CO2 is 1.8 to 2.0Nm<3> / min.t; and when the carbon content reaches a target lower limit, silicon-iron alloy is added to perform reduction and alloying treatment, and the top oxygen lance stops working till steel is tapped, wherein the bottom blowing gas is Ar, and the blowing strength of the Ar is 0.1 to 0.5Nm<3> / min.t. The problems of high dissolved oxygen content of refining end point molten steel and high oxidation in slag are solved, the consumption of alloy is reduced at the same time, and the method has remarkable economic benefit and social benefit by using the CO2 for decarburization.

Description

technical field [0001] The invention belongs to the field of out-of-furnace refining of iron and steel metallurgical technology, in particular to a VOD injection CO 2 Refining method for producing low carbon steel. Background technique [0002] VOD refining equipment is one of the main equipment for producing stainless steel. The basic principle of refining is to blow oxygen and decarburize molten steel under vacuum conditions, which is used to refine low-carbon or very low-carbon stainless steel. Originally, this process only blows oxygen at the top, and the chromium in the molten steel is seriously oxidized after the carbon content drops below 0.5%, resulting in an increase in the use of reduced alloys in the later stage. Secondly, due to the use of oxygen for decarburization, the dissolved oxygen content in the molten steel at the end of refining and the oxidative property in the slag are relatively high, resulting in a large amount of deoxidized alloys and high costs. ...

Claims

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Application Information

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IPC IPC(8): C21C7/10C21C7/068
Inventor 唐复平赵刚李德刚贾吉祥赵成林薛军
Owner ANGANG STEEL CO LTD
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