Impact resistant LLDPE composition and films made thereof
A film and dart impact technology, applied in the field of new low-density polyethylene, can solve problems such as poor optical properties and high viscosity
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[0207] The most specific methods have been described or referenced above.
[0208] The NMR sample was placed in a tube under inert gas and optionally melted. Solvent signals were used as internal standards in 1H- and 13C-NMR spectra, and their chemical shifts were converted to values relative to TMS.
[0209] As described by James. C. Randall, JMS-REV. Macromol. Chem. Phys., C29(2&3), 201-317 (1989), branches / 1000 carbon atoms are by means of 13C-NMR and are based on CH3 radicals The total agglomerate content per 1000 carbon atoms was determined. Side chains larger than CH3, in particular ethyl, butyl and hexyl side chain branches / 1000 carbon atoms, are likewise determined in this way. The degree of branching in individual polymer mass fractions was determined by the Holtrup method combined with 13C-NMR (W. Holtrup, Makromol. Chem. 178, 2335 (1977)). 13C-NMR high temperature spectra of the polymers were obtained using a Bruker DPX-400 spectrometer operating at 120°C in Fo...
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