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A kind of composite material of low styrene volatilization unsaturated polyester resin

A technology of polyester resin and composite materials, which is applied in the material field of low styrene volatilization unsaturated polyester resin, can solve the problems of product performance decline, production cost increase, unsaturated polyester production process changes, etc., to achieve reduction Styrene volatilization, cost reduction, effect of maintaining external shape

Inactive Publication Date: 2011-12-07
HENAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] At present, the process of preparing low styrene volatilization unsaturated resin has the disadvantages of greatly increasing production cost, declining product performance, and relatively large changes in the production process of unsaturated polyester.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0057] A kind of preparation method of the composite material of low styrene volatilization unsaturated polyester resin, the steps are as follows:

[0058] 1. Take 5-90% styrene and 10-95% unsaturated polyester by weight, add them to the reaction vessel, and mix and stir for 1-5 hours;

[0059] 2. According to the total weight of styrene and unsaturated polyester, add 1-25% of inorganic layered material and 0.1-10% of accelerator, mix and stir for 1-5 hours to obtain pre-intercalation;

[0060] 3. According to the total weight of styrene and unsaturated polyester, add 0.1-10% curing agent, and perform post-curing treatment for 6-12 hours.

[0061] The curing treatment is: put the material in a constant temperature drying oven at a temperature of 40°C, heat and cure for 3-6 hours, and then take it out; then put the material in a drying room at a temperature of 80°C, and cure for 3-6 hours to eliminate The internal residual stress of the material is taken out to obtain the prod...

Embodiment 1

[0072] Step 1. Take 600kg of styrene and 400kg of unsaturated polyester by weight, add them to the reaction vessel, and mix and stir for 1-5 hours;

[0073] Step 2. According to the total weight of styrene and unsaturated polyester, add 100 kg of inorganic layered material and 10 kg of accelerator into the reaction vessel, mix and stir for 1-5 hours, and obtain a pre-intercalated product;

[0074] Step 3: According to the total weight of styrene and unsaturated polyester, add 10 kg of curing agent into the reaction vessel, stir for 2-40 minutes, and release the material;

[0075] Step 4. Send the material into a constant temperature drying oven at a temperature of 40°C, heat and cure for 3-6 hours, and then take it out;

[0076] Step 5: put the material into the drying room again, at a temperature of 80°C, cure for 3-6 hours, eliminate the internal residual stress of the material, take it out, and obtain the product.

[0077] In this process, the volatilization of styrene bef...

Embodiment 2

[0079] Step 1. Take 400kg of styrene and 600kg of unsaturated polyester by weight, add them to the reaction vessel, and mix and stir for 1-5 hours;

[0080] Step 2. According to the total weight of styrene and unsaturated polyester, add 250 kg of inorganic layered material and 100 kg of accelerator into the reaction vessel, mix and stir for 1-5 hours, and obtain a pre-intercalated product;

[0081] Step 3: According to the total weight of styrene and unsaturated polyester, add 100 kg of curing agent to the reaction vessel, stir for 2-40 minutes, and release the material;

[0082] Step 4. Send the material into a constant temperature drying oven at a temperature of 40°C, heat and cure for 3-6 hours, and then take it out;

[0083] Step 5: put the material into the drying room again, at a temperature of 80°C, cure for 3-6 hours, eliminate the internal residual stress of the material, take it out, and obtain the product.

[0084] In this process, the volatilization of styrene bef...

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Abstract

The invention relates to a composite material of unsaturated polyester resins with low styrene emission. The composite material comprises, by weight, 10-95% of unsaturated polyesters, and 5-90% of styrene, and also comprises an inorganic layered material, a curing agent, and a promoter, and the percentages of the inorganic layered material, the curing agent, and the promoter respectively account for 1-25%, 0.1-10%, and 0.1-10% of a total weight of the unsaturated polyesters and styrene. The viscosity, the tensile strength, the impact strength, and the cure shrinkage of the composite material are 509-513MPa.s, 36-43MPa, 2.6-3.1Mpa, and 9.7-10.3% respectively. According to the invention, above technology is simple because the content of the unsaturated polyester resins is reduced by 60-80% in the storage phase period and is reduced by 40-70% in the curing phase period by comparing with no adding of a styrene emission inhibitor; and the cost is low, and the yield is high.

Description

[0001] technical field [0002] The invention relates to a composite material of low styrene volatilization unsaturated polyester resin, in particular to the material of low styrene volatilization unsaturated polyester resin prepared by using inorganic layered materials. Background technique [0003] Unsaturated polyester resin (UPR, Unsaturated Polyester Resins) has excellent mechanical properties, electrical properties and chemical corrosion resistance, and is easy to process. It is widely used in glass fiber reinforced materials, namely glass fiber reinforced plastics, chemical anticorrosion, casting products, sanitary ware, Arts and crafts and other industries. At present, from the perspective of material cost, resin storage, molding operation and curing characteristics, and final application performance, styrene is the most suitable monomer for unsaturated polyester resin, and the amount generally accounts for 40%-50% of the total resin. . However, styrene has a high ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/08C08K13/02C08K3/34C08K3/32C08K3/24C08K3/20C08K3/04C08K3/30C08K3/22C08F283/01
Inventor 陆昶黄新辉张长水刘泽民台玉萍张景会杜锦屏
Owner HENAN UNIV OF SCI & TECH