Film-forming pigments and coating system including the same
A coating and system technology, applied in the directions of pigment slurry, transportation and packaging, inorganic pigment treatment, etc., can solve the problems of reduced adhesion between pigment and coating film, easy decolorization, and limited scratch resistance of the coating.
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Embodiment 1
[0057] Embodiment 1: the preparation of the aluminum pigment of styrene coating
[0058] Get 480g aluminum paste (Silberline Sparkle Premium 695, non-volatile matter accounted for 75.28%), 1200mL toluene and 3mL 3-(trimethoxysilylpropyl)-2-bromo-2-methylpropionate, added to a 2L reaction bottle. The reaction mixture was heated and then heated to reflux for 24 hours. After the reaction time had elapsed, the mixture was allowed to cool to room temperature. The reaction flask was vacuum filtered and washed twice with toluene.
[0059] Take 32.3g of initiator-modified aluminum paste (containing 20g of non-volatile substances), 0.423g of CuBr, 200mL of styrene and 190mL of propylene glycol methyl ether acetate and add them to a 500mL reaction flask equipped with a mechanical stirrer and a heating mantle: use nitrogen gas The solution was degassed and heated to 80°C with continuous stirring. In a separate bottle, degas pentamethyldiethylenetriamine (PMDETA) with nitrogen for 3...
Embodiment 2
[0060] Example 2: Small amount of resinous paint formed from the polystyrene-coated aluminum of Example 1
[0061] A small amount of resin paint made from the pigment obtained in Example 1 was obtained by diluting the wet paste with propylene glycol methyl ether acetate. The pigment concentration in the final paint was 10.1% by weight. The paint was siphon-sprayed onto plastic panels made of polyethylene, poly(methyl methacrylate), and acrylonitrile-butadiene-styrene (ABS). Place the painted panels in the oven for further drying.
Embodiment 3
[0062] Embodiment 3: the preparation of the aluminum pigment of poly (methyl methacrylate) coating
[0063] Get 4.8kg aluminum paste (Silberline Sparkle Premium 695, non-volatile matter accounted for 75.68%), 12L propylene glycol methyl ether acetate and 16mL 3-(trimethoxysilylpropyl)-2-bromo-2-methylpropionate, added to a In the 20L reaction bottle of the device and the condenser. The reaction mixture was heated and then heated to reflux for 6 hours. After the reaction time had elapsed, the mixture was cooled to room temperature. The reaction flask was vacuum filtered and washed twice with propylene glycol methyl ether acetate.
[0064] Take 61.6g of initiator-modified aluminum paste (containing 40g of non-volatile matter), 0.106g of CuBr, 200mL of methyl methacrylate and 180mL of propylene glycol methyl ether acetate, and add to a 500mL reaction flask equipped with a mechanical stirrer and a heating mantle Middle: The solution was degassed with argon and heated to 80° C...
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