Thinners for aqueous suspensions of mineral particles and hydraulic binder pastes
A sum and compound technology, applied in the field of new plasticizers, can solve problems such as short time
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Embodiment 1
[0166] Embodiment 1: the preparation of glycidyl ether
Embodiment 1a
[0167] Example 1a): Preparation of 1-ethoxy-1-ethyl glycidyl ether (EEGE)
[0168] 1-Ethoxy-1-ethyl glycidyl ether was obtained by protecting glycidol with ethyl vinyl ether (EVE): 30 ml of glycidol (0.45 mol), followed by the addition of 167 ml of ethyl vinyl ether (1.6 mol). Under stirring and keeping the temperature below 40°C, 0.9 g of p-toluenesulfonic acid was gradually added. The solution was then washed with saturated NaHCO 3 The solution was washed, and the organic phase was washed with Na 2 SO 4 Dry and concentrate.
[0169] The collected monomer (EEGE) was distilled under reduced pressure (T b =86°C, 28mm) purification. When ethyl vinyl ether is used, this protection in an acid medium results in a pendant acetal linkage capable of regenerating the hydroxyl function.
[0170]
Embodiment 1b
[0171] Embodiment 1b): the preparation of glycidyl methyl ether (GME)
[0172] By distillation (T b .=110-114° C.) to purify commercially available glycidyl methyl ether (GME) ( Purity 85%), followed by CaH at +5°C 2 Store for 48 hours and filter before use.
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