The utility model discloses an anti-
disproportionation reaction rectification transformation device used in
polycrystalline silicon production, which comprises a mixer, a heater, an anti-
disproportionation fixed bed reactor and a reaction rectification
tower, the mixer receives
dichlorosilane and
liquid silicon tetrachloride and mixes the
dichlorosilane and the
liquid silicon tetrachloride to form a mixture, the mixer is connected with the heater, the heater heats the mixture, and the reaction rectification
tower is connected with the anti-
disproportionation fixed bed reactor. The method comprises the following steps of: heating a mixture, conveying the heated mixture to an anti-disproportionation
fixed bed reactor, respectively connecting the anti-disproportionation fixed
bed reactor with a heater and a reaction rectifying
tower, carrying out anti-disproportionation reaction on the mixture in the anti-disproportionation fixed
bed reactor under the action of a catalyst, connecting a tower body of the reaction rectifying tower to a mixer, and extracting
trichlorosilane from the tower top of the reaction rectifying tower,
silicon tetrachloride which does not participate in the anti-disproportionation reaction in the anti-disproportionation reaction is extracted from the tower body of the
reactive distillation tower and is conveyed to the mixer to serve as a
raw material again, and impurities generated in the reaction are discharged from the tower kettle of the
reactive distillation tower. According to the device provided by the utility model, the safety and
operability of the anti-disproportionation reaction are improved.