Manufacturing method of semi-conductive roller
A technology of semi-conductivity and manufacturing method, which is applied in the fields of electric recording process using charge pattern, equipment for electric recording process using charge pattern, and electric recording technique, and can solve problems such as uneven density and poor image density
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Embodiment 1
[0184] As the base polymer, 50 parts by mass of epichlorohydrin rubber [GECO, EPICHLOMER (registered trademark) CG102 manufactured by DAISO Co., Ltd., EO / EP / AGE=56 / 40 / 4 (molar ratio)] and chloroprene 50 parts by mass of vinyl rubber [CR, Shoprene (registered trademark) WRT manufactured by Showa Denko Co., Ltd.].
[0185] While masticating 100 parts by mass of the above base polymer with a Banbury mixer, 18.3 parts by mass of carbon black [Asahi #15 manufactured by Asahi Carbon Co., Ltd.] with an average primary particle diameter of 122 nm and the following Each component shown in Table 1 was further kneaded to prepare a rubber composition.
[0186] 【Table 1】
[0187] Table 1
[0188] Element
parts by mass
sulfur vulcanizing agent
1.50
accelerator DM
1.50
Accelerator TS
0.50
Thiourea vulcanizing agent
1.00
accelerator DT
0.85
5
acid absorber
3
...
Embodiment 2、3
[0203]
[0204] With respect to 100 parts by mass of the total amount of the base polymer, the compounding ratio of carbon black having an average primary particle diameter of 122 nm was 6.0 parts by mass (Comparative Example 1), 6.6 parts by mass (Example 2), and 30.0 parts by mass (Example 2). 3) and 32.0 parts by mass (comparative example 2), except that, it carried out similarly to Example 1, the rubber composition was prepared, and the semiconductive roller was manufactured.
Embodiment 4
[0206] As carbon black, the same amount of carbon black [Asahi #51 manufactured by Asahi Carbon Co., Ltd.] with an average primary particle diameter of 91 nm was blended, and a rubber composition was prepared in the same manner as in Example 1, thereby producing semi-conductive rollers.
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