Crystal growth atmosphere for oxyorthosilicate materials production
A technology of orthosilicate and crystal, which is applied in the field of crystal growth and can solve problems such as reduced scintillation efficiency
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[0011] Controlling the atmosphere above the melt during crystal growth using methods such as the Chowklarski method can be critical to controlling growth stability and controlling the properties of the growing crystal. Especially in the growth of rare earth oxyorthosilicate scintillation crystals, careful control of the atmosphere and melt composition can simultaneously minimize at least three problems in these crystal growths.
[0012] The first problem is that the grown crystal contains oxygen vacancies, which reduce the crystal's scintillation efficiency and cause an undesired crystal continuation known as afterglow. These oxygen vacancies may arise from oxygen deficiency during crystal growth. Rare earth oxyorthosilicate scintillation crystals can be prepared by melting rare earth compounds (such as oxides) and silicon oxides (such as SiO 2 ) prepared by melt growth. Melting these substances may require temperatures of 2000°C or higher. At this temperature, it is advisa...
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