Optical adhesive composition and display panel including the same
A technology of optical adhesives and compositions, applied in the direction of adhesive types, polyurea/polyurethane adhesives, adhesives, etc., capable of solving problems such as adhesive overflow
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preparation example 1
[0064] Preparation Example 1: Preparation of Polyurethane Acrylate Resin
[0065] 933.01g (equivalent: 1) of polypropylene glycol (PPG 3000), 47.64g (equivalent: 0.69) of isophorone diisocyanate (IPDI) and 3.66g (equivalent: 0.03) of 1,3,6-hexaethylene Methyl triisocyanate was added to a 1L four-necked flask equipped with a stirrer and a thermometer connected to a reaction controller, a condenser, and a nitrogen inlet pipe, and polymerized at 70° C. for 3 hours. While nitrogen gas was supplied at 10 cc / min, 15.44 g (equivalent: 0.16) of 2-isocyanatoethyl methacrylate was added into the flask, and reacted at 45° C. for 3 hours. After confirming the absorption spectrum of isocyanate with FT-IR (2770cm -1 ) disappeared, the reaction was terminated. Thus, a urethane acrylate resin having hydroxyl and vinyl groups was obtained.
preparation example 2
[0066] Preparation Example 2: Preparation of Polyurethane Acrylate Resin
[0067]924.5g (equivalent: 1) of polypropylene glycol (PPG 3000), 47.2g (equivalent: 0.69) of isophorone diisocyanate (IPDI) and 3.6g (equivalent: 0.03) of 1,3,6-hexaethylene Methyl triisocyanate was charged into the same flask as in Preparation Example 1, and polymerized at 70° C. for 3 hours. While supplying nitrogen gas at 10 cc / min, 15.3 g (equivalent: 0.16) of 2-isocyanatoethyl methacrylate and 9.1 g (equivalent: 0.06) of 3-isocyanatopropyltriethoxysilane were added into the flask and react at 45°C for 3 hours. After confirming the absorption spectrum of isocyanate with FT-IR (2770cm -1 ) disappeared, the reaction was terminated. Thus, a urethane acrylate resin having hydroxyl, vinyl and silyl groups is obtained.
preparation example 3
[0068] Preparation Example 3: Preparation of Polyurethane Acrylate Resin
[0069] Prepare the urethane acrylate resin with hydroxyl group and vinyl group with the same method as Preparation Example 1, difference is to use the polypropylene glycol (PPG 3000) of 940.27g (equivalent: 1), the isophorone of 48.01g (equivalent: 0.69) Diisocyanate (IPDI), 3.69 g (equivalent: 0.03) of 1,3,6-hexamethylene triisocyanate and 7.78 g (equivalent: 0.08) of 2-isocyanatoethyl methacrylate.
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