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Low-radiation heat-treatable coated glass and interlayer glass product thereof

A low-emissivity coating and glass technology, applied in the direction of glass/slag layered products, layered products, metal layered products, etc., can solve the problem that the thermal stability of the film layer and the barrier ability of oxygen atoms are not enough, and the ZnMgO film layer cannot be used as a protection Insufficient sealing effect of dielectric layer and dielectric layer to achieve the effect of increasing visible light transmittance, improving microstructural structure, and reducing non-uniform defects

Active Publication Date: 2014-08-20
FUYAO GLASS IND GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the ZnSnOx film material has the following disadvantages: first, the chemical stability is not good, and it is easy to be chemically corroded; second, the haze of the constructed silver-based low-emissivity coating product is high after high temperature heat treatment; third, the ZnSnOx dielectric layer is closed Insufficient effect causes the double silver or triple silver film system to be easily damaged by sodium ions, oxygen atoms and other impurity atoms from the glass surface during heat treatment, making the coated glass present a partially non-uniform cloudy appearance after heat treatment
[0004] In the prior art, there is a technology of introducing magnesium atoms (Mg) into the film layer of coated glass. For example, the US patent application US20100167034 (A1) discloses ZnMgO alloy oxides, in which the atomic number ratio of Mg / Zn does not exceed 15% However, this ZnMgO film layer cannot be used as the main body of the protective dielectric layer; another example is the use of Mg, Zn, Al, In, Sn, Sb and Bi metal thin layers (1 nanometer to 10 nanometers) as proposed in US Patent No. 7,507,478 (B2). The stable layer of the sub-stoichiometric ratio layer, as well as the Mg-doped SnO2 film layer disclosed in U.S. Patent US5962115 (A) as the upper dielectric layer of the low-e film system, but the thermal stability of this film layer and the oxygen atom Barrier ability is still not enough

Method used

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  • Low-radiation heat-treatable coated glass and interlayer glass product thereof
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  • Low-radiation heat-treatable coated glass and interlayer glass product thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~4

[0049] Explain that when ZnSnMgOx film layer or ZnSnNiOx film layer are arranged on the third dielectric layer in double-silver low-emissivity coated glass, or are arranged on the fourth dielectric layer in three-silver low-emissivity coated glass, relative to ZnSnOx film layer to low-emissivity coating Improved chemical stability.

[0050] Sodium-calcium silicate float green glass with a thickness of 2.1 mm is used as the substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for coating deposition. The background vacuum is higher than 6×10 -4 Pa. Wherein as shown in table 2, on the glass substrate of comparative example 1 and embodiment 1,2, deposit the double silver film layer listed in table 2 successively; As shown in table 3, in comparative example 2 and embodiment 3,4 The three silver film layers listed in Table 3 were sequentially deposited on the glass substrate.

[0051] As can be seen from Table 2, the difference bet...

Embodiment 5~8

[0062] It shows that the ZnSnMgOx film layer or the ZnSnNiOx film layer is arranged in the double-silver low-emissivity coated glass to improve the thermal stability of the double-silver low-emissivity coating.

[0063] Sodium-calcium silicate float green glass with a thickness of 2.1 mm is used as the substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for coating deposition. The background vacuum is higher than 6×10 -4 Pa. Wherein, as shown in Table 4, the double silver film layers listed in Table 4 were sequentially deposited on the glass substrates of Comparative Example 3 and Examples 5-8.

[0064] It can be seen from Table 4 that the difference between Examples 5-8 and their corresponding Comparative Example 3 is that the first dielectric layer, the second dielectric layer and the third dielectric layer in Comparative Example 3 are mainly ZnSnOx film layers, and in Example 5 The ZnSnOx film layers of the first dielectri...

Embodiment 9~14

[0072] It shows that the ZnSnMgOx film layer or the ZnSnNiOx film layer arranged in the triple-silver low-emissivity coated glass can improve the thermal stability of the triple-silver low-emissivity coating.

[0073] Sodium-calcium silicate float green glass with a thickness of 2.1 mm is used as the substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for coating deposition. The background vacuum is higher than 6×10 -4 Pa. Wherein as shown in table 5, on the glass substrate of comparative example 4 and embodiment 9~11 deposit three silver film layers listed in table 5 successively; As shown in table 6, on the glass substrate of embodiment 12~14 The three silver film layers listed in Table 6 were deposited sequentially.

[0074]From Table 5 and Table 6, it can be seen that the difference between Examples 9-14 and their corresponding Comparative Example 4 is that the first, second, third and fourth dielectric layer main bodies ...

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Abstract

The invention relates to the field of glass coating, in particular to heat-treatable silver-based low-radiation coated glass and an interlayer glass product thereof. The low-radiation coated glass comprises a glass substrate, wherein multiple medium layers and at least two infrared reflecting layers are outwards arranged on the surface of the glass substrate; at least one layer of the multiple medium layers comprises a ZnSnMgOx coating layer or ZnSnNiOx coating layer. According to the low-radiation coated glass and the interlayer glass product thereof, as the ZnSnMgOx coating layer or ZnSnNiOx coating layer is introduced to the medium layer, the chemical stability and the heat stability of the low-radiation coated glass and the interlayer glass product are remarkably improved, and the constructed double-silver-layer or three-silver-layer low-radiation coating has higher heat stability; and the growth of Zn and Sn large grains is restrained as Mg or Ni is introduced to an alloy target, the microscopic structure of the target is improved, and the stability of the sputtering process is favorably improved.

Description

Technical field: [0001] The invention relates to the field of glass coating, in particular to a silver-based low-emissivity coated glass with high visible light transmittance, high infrared reflectivity and heat treatment and its laminated glass products, especially double-silver or Triple silver low-e coated glass. Background technique: [0002] Low-emissivity (low-e) coated glass has the advantages of passing through visible light and reflecting infrared rays, which can significantly reduce the energy consumption of air-conditioning in cars and improve the comfort of drivers and passengers. Therefore, it is used as a green product in construction and transportation. There is a huge market demand for tools. With the development of technology, double-silver and triple-silver low-emissivity coated glass have appeared after single-silver low-emissivity coated glass. Double-silver and triple-silver low-emissivity coated glass has two or three infrared reflection layers (genera...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C17/36B32B17/06B32B15/04C03C27/12
CPCC03C17/366C03C17/3626C03C17/3639C03C17/3644
Inventor 曹晖袁军林林柱朱谧何立山卢国水彭颖昊福原康太
Owner FUYAO GLASS IND GROUP CO LTD