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Separation and purification method of raffinose

A technology for separation and purification of raffinose, applied in the field of chemical engineering, to achieve the effects of low cost, good stability and long service life

Active Publication Date: 2015-03-04
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] In order to overcome the defects of existing methods such as ultrafiltration membrane method and heavy metal salt to denature protein and remove protein, the present invention provides an environmentally friendly, simple and efficient method for separating raffinose. The exclusion function of solute realizes the efficient separation of macromolecular impurities such as raffinose and cottonseed protein

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The degreased cottonseed meal is percolated and extracted with ethanol aqueous solution with a volume fraction of 75% to obtain a raffinose extract, and the gossypol and other pigments in the raffinose extract are removed by activated carbon decolorization, and the decolorized solution is further concentrated to obtain concentrated raffinose liquid. Add water to the raffinose concentrate to make a raw material solution with a solid concentration of 200 mg / mL, use Sephadex G-10 (dextran gel, molecular weight exclusion 700) as a filler, and fully swell it with 20% ethanol aqueous solution , using the wet packing method to pack the gel chromatographic column, the chromatographic column size is Φ1.6cm×33cm, and the chromatographic column volume (BV) is 66.3ml. Take 0.02BV of the raw material solution and load it on the packed gel chromatography column. After the sample loading is completed, flow through the gel chromatography column with a volume fraction of 20% ethanol aqu...

Embodiment 2

[0037] The degreased cottonseed meal is percolated and extracted with ethanol aqueous solution with a volume fraction of 75% to obtain a raffinose extract, and the gossypol and other pigments in the raffinose extract are removed by activated carbon decolorization, and the decolorized solution is further concentrated to obtain concentrated raffinose liquid. Add water to the raffinose concentrate to make a raw material solution with a solid concentration of 500mg / mL, use Sephadex LH-20 (hydroxypropyl dextran gel, exclusion molecular weight 4000-5000) After the ethanol aqueous solution is fully swollen, the gel chromatographic column is packed by the wet packing method. The chromatographic column size is Φ1.6cm×33cm, and the chromatographic column volume (BV) is 66.3ml. Take 0.1BV of the raw material solution and load it on the packed gel chromatography column. After the sample loading is completed, use 30% ethanol aqueous solution to flow through the gel chromatography column at...

Embodiment 3

[0039] The degreased cottonseed meal is percolated and extracted with ethanol aqueous solution with a volume fraction of 75% to obtain a raffinose extract, and the gossypol and other pigments in the raffinose extract are removed by activated carbon decolorization, and the decolorized solution is further concentrated to obtain concentrated raffinose liquid. Add water to the raffinose concentrate to make a raw material solution with a solid content concentration of 800 mg / ml, use Sephadex G-50 (dextran gel, exclusion molecular weight range is 1000-5000) as filler, and pass through ethanol with a volume fraction of 30%. After the aqueous solution is fully swollen, the gel chromatographic column is packed by the wet packing method. The chromatographic column size is Φ1.6cm×33cm, and the chromatographic column volume (BV) is 66.3ml. Take 0.05BV of the raw material solution and load it on the packed gel chromatography column. After the sample loading is completed, flow through the g...

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Abstract

The invention discloses a separation and purification method of raffinose. The separation and purification method of the raffinose includes: 1) filling a gel chromatography column with gel serving as fillers by a wet process; 2) preparing raw material liquid from raffinose concentrated solution, and introducing raw material liquid into the gel chromatography column, wherein the raffinose concentrated solution is obtained by extracting to obtain raffinose extracting solution from degreased cottonseed meal by water or alcohol water solution and subjecting the raffinose extracting solution to activated carbon decoloration and concentration; and 3) eluting with deionized water or ethanol water as eluant, collecting eluant containing the raffinose, and obtaining purified raffinose after rotary evaporation. Gel chromatography is used for separating the raffinose from protein and the like, and the separation and purification method of the raffinose is simple in technological process, simple and convenient to operate, high in separation efficiency and capable of achieving reusability of the fillers and has wide industrialized application prospect.

Description

technical field [0001] The invention relates to the technical field of chemical engineering, in particular to a method for separating and purifying raffinose. Background technique [0002] Raffinose, also known as Melitriose or raffinose, is composed of galactose, glucose and fructose. It is an oligosaccharide and a non-reducing sugar. Research has found that raffinose is an excellent nutrient source for beneficial bacteria such as Bifidobacterium and Lactobacillus acidophilus in the human intestinal tract, which can promote their proliferation, thereby inhibiting the growth of spoilage bacteria in the intestinal tract and reducing the formation of toxic fermentation products . Bifidobacteria ferment raffinose to produce a large amount of short-chain fatty acids, which can stimulate intestinal peristalsis, increase feces moistness and maintain a certain osmotic pressure, thereby preventing constipation. In addition, raffinose can improve the digestive function of the human...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07H3/06C07H1/06
Inventor 鲍宗必刘聪邢华斌苏宝根任其龙杨亦文杨启炜
Owner ZHEJIANG UNIV