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Mg-Sn-Al wrought magnesium alloy and preparation method thereof

A wrought magnesium alloy, mg-sn-al technology, applied in the field of metal materials, can solve the problems of restricting development, high cost, high price, etc.

Inactive Publication Date: 2013-05-22
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Due to the exhaustion of energy sources, people's pursuit of lightweight has made magnesium alloys a research hotspot. There are not many effective alloying elements for magnesium alloys. There are only a few good ones such as: Al, Zn, RE (rare earth elements) Among them, magnesium alloys containing Al develop into AZ series magnesium alloys, but they can only be used at room temperature; magnesium alloys containing Zn and the addition of trace alloying element Zr develop into ZK series magnesium alloys, which are mainly used in superalloys. However, due to the burning loss of Zr, its cost is high, which restricts its development; and the magnesium alloy containing RE develops into a rare earth magnesium alloy, and a system with excellent performance (Mg-RE-Zn) is formed after adding Zn element at the same time. Because the price of RE is relatively expensive, it is not easy to be widely used in civilian fields
However, as rare earth resources become less and less, their prices become more and more expensive. Therefore, there is an urgent need to develop high-performance magnesium alloys that do not contain rare earths, hoping to be used at higher temperatures, so now Many researchers at home and abroad are committed to the research and development of magnesium alloys with new systems (excluding rare earths)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] 1) Weigh the following components according to weight percentage: Sn: 4%; Al: 1%; Mn: 0.2% (in the form of 4% magnesium-manganese alloy); the balance is Mg.

[0013] 2) Under the protection of the covering agent, first smelt industrial pure magnesium and industrial pure aluminum between 720°C and 740°C. After they are completely melted and the temperature rises to 720°C and stabilizes, add industrial pure tin preheated to 150°C And preheat the magnesium-manganese master alloy to 200°C, add the refining agent hexachloroethane and stir thoroughly for 3-6 minutes, let the melt stand at 720°C for 10-20 minutes, and knock off the scum on the surface, It is poured into an iron mold preheated to 250-300°C under certain conditions to prepare an ingot.

[0014] 3) The prepared magnesium ingot was covered with graphite, homogenized at 500° C. for 24 hours, and then quenched in water to obtain a homogenized sample.

[0015] 4) Preheat the homogenized magnesium ingots and wagons a...

Embodiment 2

[0017] 1) Weigh the following components according to weight percentage: Sn: 5%; Al: 1%; Mn: 0.2% (in the form of 4% magnesium-manganese alloy); the balance is Mg.

[0018] 2) Under the protection of the covering agent, first smelt industrial pure magnesium and industrial pure aluminum between 720°C and 740°C. After they are completely melted and the temperature rises to 720°C and stabilizes, add industrial pure tin preheated to 150°C Preheat the magnesium-manganese master alloy to 200°C, add the refining agent hexachloroethane and stir thoroughly for 3-6 minutes, let the melt stand at 720°C for 10-20 minutes, and remove the scum on the surface. It is poured into an iron mold preheated to 250-300°C under conditions to prepare an ingot.

[0019] 3) The prepared magnesium ingot was covered with graphite, homogenized at 500° C. for 24 hours, and then quenched in water to obtain a homogenized sample.

[0020] 4) Preheat the homogenized magnesium ingots and wagons at 300°C for 2 h...

Embodiment 3

[0022] 1) Weigh the following components according to weight percentage: Sn: 5%; Al: 1%; Mn: 0.2% (in the form of 4% magnesium-manganese alloy); Zn: 1%; the balance is Mg.

[0023] 2) Under the protection of the covering agent, first smelt industrial pure magnesium and industrial pure aluminum between 720°C and 740°C. After they are completely melted and the temperature rises to 720°C and stabilizes, add industrial pure tin preheated to 150°C And preheat the magnesium-manganese master alloy to 200°C, add zinc at the same time, and add the refining agent hexachloroethane to stir for 3-6 minutes, let the melt stand at 720°C for 10-20 minutes, and knock off the scum on the surface , poured into an iron mold preheated to 250-300°C under the condition of 720°C to prepare an ingot.

[0024] 3) The prepared magnesium ingot was covered with graphite, homogenized at 520° C. for 24 hours, and then quenched in water to obtain a homogenized sample.

[0025] 4) Preheat the homogenized mag...

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Abstract

The invention belongs to the field of magnesium alloy design. An Mg-Sn-Al ternary alloy belongs to a novel wrought magnesium alloy and consists of the following raw materials in percentage by mass: 4.00-10.00% of industrial pure tin, 1.00-6.00% of industrial pure aluminum, and the balance of industrial pure magnesium and unavoidable impurities. A preparation method of the wrought magnesium alloy comprises the steps of firstly melting magnesium and aluminum, then adding tin and a microalloying element, namely manganese or zinc, pouring to form cast ingots after stirring and refining, carrying out homogenizing treatment on the cast ingots, and extruding the cast ingots to obtain corresponding extruded sections. The wrought magnesium alloy and the preparation method are characterized in that the novel wrought magnesium alloy with relatively good strength and toughness is prepared from the raw materials, namely the aluminum and the tin, which are both relatively low in cost and melting point, and the strength and the toughness are equivalent to a commercial high-strength magnesium alloy ZK60.

Description

technical field [0001] The invention relates to the field of metal materials, in particular to a rare earth-free deformed magnesium alloy with both strength and toughness and a preparation method thereof. Background technique [0002] Due to the exhaustion of energy sources, people's pursuit of lightweight has made magnesium alloys a research hotspot. There are not many effective alloying elements for magnesium alloys. There are only a few good ones such as: Al, Zn, RE (rare earth elements) Among them, magnesium alloys containing Al develop into AZ series magnesium alloys, but they can only be used at room temperature; magnesium alloys containing Zn and the addition of trace alloying element Zr develop into ZK series magnesium alloys, which are mainly used in superalloys. However, due to the burning loss of Zr, its cost is high, which restricts its development; and the magnesium alloy containing RE develops into a rare earth magnesium alloy, and a system with excellent perfo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C23/00C22C1/03C22C1/06C22F1/06
Inventor 潘复生佘加汤爱涛
Owner CHONGQING UNIV
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