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Ni-based single crystal superalloy and alloy member obtained from the same

A superalloy and single crystal technology, applied in the field of new Ni-based single crystal superalloys, can solve the problems of increased TCP phasor, decreased creep strength, and difficulties in the development of Ni-based single crystal superalloys

Inactive Publication Date: 2014-01-08
NAT INST FOR MATERIALS SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, since the composition ratio of Re (5% by mass or more) exceeds the solid solution amount of Re in the parent phase (γ phase), there is a problem that the remaining Re combines with other elements to precipitate the so-called TCP phase (Topologically Close Packed phase), and due to long-term use at high temperature, the amount of the TCP phase increases and the creep strength decreases
As shown in the above examples, it is difficult to develop Ni-based single crystal superalloys that have both life at high temperatures, strength, and oxidation resistance, and this will become an important technical problem for the practical use of heat-resistant alloys in the future.

Method used

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  • Ni-based single crystal superalloy and alloy member obtained from the same
  • Ni-based single crystal superalloy and alloy member obtained from the same
  • Ni-based single crystal superalloy and alloy member obtained from the same

Examples

Experimental program
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Effect test

Embodiment

[0087] Next, examples are shown to illustrate the effects of the present invention.

[0088] A vacuum melting furnace is used to adjust the molten metal of various Ni-based single crystal superalloys, and use the alloy molten metal to cast multiple alloy ingots with different compositions. The alloys of the present invention (Examples 1-3) and six representative existing heat-resistant alloys (Reference Examples 1-6) and four of the fourth and fifth-generation heat-resistant alloys ( The composition ratio of Reference Example 7-11) (Patent Documents 6 and 7) is shown in Table 2 together.

[0089] [Table 2]

[0090]

[0091] Then, the alloy ingot is subjected to solution treatment and aging treatment, and the state of the alloy structure is observed through a scanning electron microscope (SEM). In the solution treatment of the alloys of Examples 1-3 and Reference Examples 7-11, after holding at 1573K (1300°C) for 1 hour, the temperature was raised to 1603K (1330°C) and held for 5 ho...

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Abstract

Provided is an Ni-based single crystal superalloy wherein the ingredients have a composition containing, as ratio by mass, from 5.0% by mass to 7.0% by mass of Al, from 4.0% by mass to 8.0% by mass of Ta, from 0% by mass to 2.0% by mass of Mo, from 3.0% by mass to 8.0% by mass of W, from 3.0% by mass to 8.0% by mass of Re, from 0% by mass to 0.50% by mass of Hf, from 3.0% by mass to 7.0% by mass of Cr, from 0% by mass to 9.9% by mass of Co and from 1.0% by mass to 10.0% by mass of Ru, with the balance of Ni and inevitable impurities. The alloy prevents TCP phase precipitation at high temperatures, therefore having improved strength at high temperatures and having oxidation resistance at high temperatures. The above-mentioned first-generation alloy CMSX-2 and second-generation alloy CMSX-4 are, though comparable thereto in point of creep strength at low temperatures, inferior to third-generation alloys in point of creep strength at high temperatures, since a large quantity of eutectic ³'-phase remains therein even after high-temperature solution treatment.

Description

[0001] This application is a divisional application of the application with the application number 200980124215.1 and the invention title of "Ni-based single crystal superalloy and alloy components obtained therefrom" filed by the applicant on June 26, 2009. Technical field [0002] The invention relates to a new Ni-based single crystal superalloy, which uses Al, Ta, W, Re, Cr and Ru as main additional elements, and has excellent high-temperature creep characteristics and high-temperature corrosion resistance and other environmental resistance. Background technique [0003] Among the representative compositions of Ni-based single crystal superalloys developed as materials for moving and static blades at high temperatures such as aircraft and gas turbines, for example, the compositions described in Table 1 are cited. [0004] [Table 1] [0005] [0006] In the above-mentioned Ni-based single crystal superalloy, a solution (Japanese: solution) treatment is performed at a predetermined t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05
CPCC22C19/057
Inventor 原田广史小泉裕小林敏治横川忠晴坂本正雄川岸京子北岛具教叶安洲
Owner NAT INST FOR MATERIALS SCI