High-strength hot-dip galvanized steel sheet excellent in coating adhesion and manufacturing method thereof
A hot-dip galvanized steel sheet, coating and sealing technology, applied in hot-dip coating process, manufacturing tools, heat treatment furnaces, etc. Excellent effect
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Embodiment 1
[0121] The cast slabs obtained by melting the steels having the chemical components shown in Table 1 were hot-rolled, pickled, and then cold-rolled to form cold-rolled steel sheets with a thickness of 1.2 mm.
[0122] [Table 1]
[0123] (quality%)
[0124] steel mark C Si mn Cr P S A 0.03 0.5 2.0 0.1 0.01 0.001 B 0.05 1.0 2.0 0.1 0.01 0.001 C 0.07 1.2 1.9 0.1 0.01 0.001 D 0.08 1.5 1.2 0.2 0.01 0.001 E 0.09 1.5 2.3 0.2 0.01 0.001 F 0.12 1.5 2.5 0.2 0.01 0.001 G 0.09 1.5 1.4 0.02 0.01 0.001 H 0.08 1.5 2.7 0.02 0.01 0.001 I 0.11 1.5 2.7 0.02 0.01 0.001 J 0.09 1.0 1.8 0.6 0.01 0.001 K 0.11 2.3 1.9 0.2 0.01 0.001 L 0.12 1.2 3.2 0.1 0.01 0.001
[0125] Thereafter, the above-mentioned cold-rolled steel sheet was heated by appropriately changing the outlet temperature of the oxidation furnace by a CGL having a DFF type oxidation furnace. The di...
Embodiment 2
[0139] The cast slabs obtained by melting the steels having the chemical components shown in Table 1 were hot-rolled, pickled, and then cold-rolled to form cold-rolled steel sheets with a thickness of 1.2 mm.
[0140] Thereafter, oxidation treatment and reduction annealing were carried out in the same manner as in Example 1. In addition, the amount of coating was adjusted to about 50 g / m by the gas friction contact method after performing hot-dip plating in a galvanizing bath at 460°C with the added amount of Al adjusted to 0.13%. 2 , alloying treatment was carried out at the predetermined temperature shown in Table 3 for 20 to 30 seconds.
[0141] For the hot-dip galvanized steel sheet obtained as described above, the amount of plating deposition and the Fe content in the plating layer were determined. In addition, quantification of Si and Mn of oxides contained in the plating layer and from the surface layer of the steel sheet under the plating layer to the steel sheet with...
Embodiment 3
[0157] The cast slabs obtained by melting the steels having the chemical components shown in Table 1 were hot-rolled, pickled, and then cold-rolled to form cold-rolled steel sheets with a thickness of 1.2 mm.
[0158] Thereafter, oxidation treatment, reduction annealing, plating, and alloying treatment were performed in the same manner as in Example 2. However, among these, the inside of the oxidation furnace is divided into three areas, and the temperature on the outlet side and the oxygen concentration in the atmosphere are adjusted by variously changing the respective combustion rates and air ratios.
[0159] For the hot-dip galvanized steel sheet obtained as described above, the plating deposition amount and the Fe content in the plating layer were determined. Furthermore, quantification of Si and Mn of oxides contained in the coating layer and from the surface layer of the steel sheet under the coating layer to 5 μm inside the steel sheet was carried out, and the appearan...
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