High-heat-resistance and low-expansion-coefficient carbon fiber vinyl ester composite material and preparation method thereof

A low-expansion coefficient, vinyl ester technology, applied in the field of high heat-resistant and low-expansion coefficient carbon fiber vinyl ester composite materials and preparation, can solve the problems of high heat resistance and small expansion coefficient, affecting production and life, poor equipment stability, etc. , to achieve the effect of low shrinkage, low production cost and high tensile strength

Inactive Publication Date: 2014-06-11
YUZHOU YUANDA PLASTIC ELECTRICAL APPLIANCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Restricted by the material of the matrix itself, the composite material of the non-metallic matrix has the characteristics of low specific gravity, heat resistance, and large expansion coefficient, while the composite material of the metal matrix has the characteristics of large specific gravity, high heat resistance, small expansion coefficient, and zero shrinkage. In real life, precision components in high-heat working environments, such as IT equipment, experimental instruments, audio and video components, etc., require materials to have high heat resistance, small expansion coefficient, zero shrinkage, and low specific gravity. The composite materials of metal matrix and non-metal matrix cannot meet the demand at the same time, which often leads to problems such as poor stability and low accuracy of the equipment, which seriously affects normal production and life.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A carbon fiber vinyl ester composite material with high heat resistance and low expansion coefficient, which is made of each component according to the following weight: vinyl resin 40kg, glass fiber 20kg, carbon fiber powder 40kg, inorganic mineral filler 70kg, magnesium oxide 2kg, Molding agent 2kg, curing agent 1kg.

[0022] The vinyl resin is epoxy vinyl resin or flexible vinyl ester resin.

[0023] The inorganic mineral filler is one or more of calcium carbonate, aluminum hydroxide, talc, kaolin, bentonite or mica.

[0024] The said release agent is one of silicone oil, polyethylene glycol or low molecular weight polyethylene.

[0025] The curing agent is diaminodiphenyl sulfone or m-xylylenediamine.

[0026] The preparation method of the high heat resistance and low expansion coefficient carbon fiber vinyl ester composite material includes the following steps:

[0027] Step 1. Stirring: Put vinyl resin, carbon fiber powder, inorganic mineral filler, release agent and curing...

Embodiment 2

[0033] A carbon fiber vinyl ester composite material with high heat resistance and low expansion coefficient, which is made of each component according to the following weight: vinyl resin 45kg, glass fiber 25kg, carbon fiber powder 60kg, inorganic mineral filler 80kg, magnesium oxide 3kg, Molding agent 4kg, curing agent 2kg.

[0034] The vinyl resin is epoxy vinyl resin or flexible vinyl ester resin.

[0035] The inorganic mineral filler is one or more of calcium carbonate, aluminum hydroxide, talc, kaolin, bentonite or mica.

[0036] The said release agent is one of silicone oil, polyethylene glycol or low molecular weight polyethylene.

[0037] The curing agent is diaminodiphenyl sulfone or m-xylylenediamine.

[0038] The preparation method of the high heat resistance and low expansion coefficient carbon fiber vinyl ester composite material includes the following steps:

[0039] Step 1. Stirring: Put vinyl resin, carbon fiber powder, inorganic mineral filler, release agent and curing...

Embodiment 3

[0045] A carbon fiber vinyl ester composite material with high heat resistance and low expansion coefficient, which is made of each component according to the following weight: vinyl resin 50kg, glass fiber 30kg, carbon fiber powder 70kg, inorganic mineral filler 90kg, magnesium oxide 5kg, Molding agent 6kg, curing agent 3kg.

[0046] The vinyl resin is epoxy vinyl resin or flexible vinyl ester resin.

[0047] The inorganic mineral filler is one or more of calcium carbonate, aluminum hydroxide, talc, kaolin, bentonite or mica.

[0048] The said release agent is one of silicone oil, polyethylene glycol or low molecular weight polyethylene.

[0049] The curing agent is diaminodiphenyl sulfone or m-xylylenediamine.

[0050] The preparation method of the high heat resistance and low expansion coefficient carbon fiber vinyl ester composite material includes the following steps:

[0051] Step 1. Stirring: Put vinyl resin, carbon fiber powder, inorganic mineral filler, mold release agent and c...

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Abstract

The invention discloses a high-heat-resistance and low-expansion-coefficient carbon fiber vinyl ester composite material and a preparation method thereof. The composite material is prepared by carrying out a series of procedures, including stirring, spreading and molding on the following components in parts by weight: 40-50 parts of vinyl resin, 20-30 parts of glass fiber, 40-70 parts of carbon fiber powder, 70-90 parts of inorganic mineral filler, 2-5 parts of magnesium oxide, 2-6 parts of a mold release agent and 1-3 parts of a curing agent. The high-heat-resistance and low-expansion-coefficient carbon fiber vinyl ester composite material has the advantages of simple composition, convenience in preparation, properties of a metal substrate and a nonmetallic substrate, wider application range, simple and convenient steps, simple equipment, convenience in implementation and popularization, low production cost and very high economic benefit. The properties of high temperature resistance, noninflammability, corrosion resistance, heat resistance, high sound insulating property, high tensile strength and high electrical insulating property of glass fiber are fully used and the properties of low dead weight and high strength of carbon fiber are fully utilized, and high heat resistance, small expansion coefficient and low contraction rate are realized on the premise of ensuring low specific weight.

Description

Technical field [0001] The invention belongs to the technical field of polymer materials, and particularly relates to a carbon fiber vinyl ester composite material with high heat resistance and low expansion coefficient and a preparation method. Background technique [0002] Composite materials are composed of two or more materials with different properties, through physical or chemical methods, macroscopically composed of materials with new properties. It makes full use of the advantages of various materials to complement each other in performance and produce a synergistic effect, so that the comprehensive performance of the composite material is better than the original constituent materials to meet various requirements. Composite materials are divided into two categories: metal and non-metal based on the matrix material. Among them, the non-metal matrix mainly includes synthetic resin, rubber, ceramic, graphite, carbon and so on. Commonly used metal substrates are aluminum, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/10C08L101/06C08K13/04C08K7/14C08K7/06C08K3/22B29C70/34
Inventor 朱亮朱冠军
Owner YUZHOU YUANDA PLASTIC ELECTRICAL APPLIANCE
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