Mesoporous Silica and Its Support Catalyst for Gas Phase Oxylation of Propylene Butyraldehyde
A technology of mesoporous silica and oxo synthesis, applied in the direction of silica, organic compound/hydride/coordination complex catalyst, physical/chemical process catalyst, etc., can solve the problem of unsatisfactory catalytic effect and demanding operating indicators , complex process and other problems, to achieve the effect of solving the difficulty of separating the catalytic system and the product
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Embodiment 1
[0037] 1) Preparation of carrier mesoporous silica
[0038] Take 45mL of hexadecane bromide (0.148mol) and 30mL of acetone into a three-necked flask, stir evenly with a magnetic force, put in a constant temperature water bath at 80°C, take 11mL of tetramethylethylenediamine (0.074mol) in a constant pressure dropping funnel , Drop by drop, heated to reflux for 48h. Cooled to room temperature to obtain a white powdery solid, washed 3 times with an appropriate amount of acetone, filtered and dried to obtain template C 16 -2-C 16 51.2 g.
[0039] The reaction equation is as follows:
[0040]
[0041] Template C was prepared by 8.4g (0.012mol) 16- 2-C 16Dissolve in 150mL of water, heat to 45°C, and stir evenly until it is completely dissolved. Add 6.2mL of tetraethyl orthosilicate (0.028mol) to the obtained colloidal solution, and add 0.1M NaOH solution dropwise to adjust the pH to 4.5. After fully stirring and mixing evenly, place the solution in a high-temperature reacti...
Embodiment 2
[0046] 1) Preparation of carrier mesoporous silica
[0047] Take 30mL of hexadecane bromide (0.098mol) and 25mL of acetone into a three-necked flask, stir evenly with a magnetic force, place in a constant temperature water bath at 90°C, take 6.6mL of tetramethylethylenediamine (0.044mol) in a constant pressure dropping funnel , drop by drop and heated to reflux for 48h. Cooled to room temperature to obtain a white powdery solid, washed 3 times with an appropriate amount of acetone, filtered and dried to obtain template C 16 -2-C 16 32.7g.
[0048] Template C was prepared from 12.9 g 16 -2-C 16 (0.018mol) was dissolved in 240mL of water, heated to 45°C, and stirred evenly until it was completely dissolved, and 11.2mL of tetraethyl orthosilicate (0.050mol) was added to the obtained colloidal solution, and 0.1M NaOH was added dropwise Adjust the pH of the solution to 5.5, stir and mix well, place the solution in a high-temperature reaction kettle, and crystallize at 90°C for...
Embodiment 3
[0053] 1) Preparation of carrier mesoporous silica
[0054] Take 40mL hexadecane bromide (0.131mol) and 30mL acetone into a three-necked flask, stir evenly with a magnetic force, place in a constant temperature water bath at 85°C, take 9.3mL tetramethylethylenediamine (0.063mol) in a constant pressure dropping funnel , drop by drop and heated to reflux for 48h. Cooled to room temperature to obtain a white powdery solid, washed 3 times with an appropriate amount of acetone, filtered and dried to obtain template C 16 -2-C 16 42.7 g.
[0055] Template C was prepared from 9.5 g 16 -2-C 16 (0.013mol) was dissolved in 240mL water, heated to 45°C, and stirred evenly until it was completely dissolved, and 7.3mL tetraethyl orthosilicate (0.033mol) was added to the obtained colloidal solution, and 0.1M NaOH was added dropwise Adjust the pH of the solution to 5.0, stir and mix well, place the solution in a high-temperature reaction kettle, and crystallize at 95°C for 12 hours; cool ...
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