A sulfur-resistant methanation process for producing natural gas from syngas
A technology for sulfur-resistant methanation and synthesis gas, which is applied in the petroleum industry, gas fuel, fuel, etc., can solve the problems of intolerant sulfur, easy poisoning and inactivation, etc., achieves good isothermal resistance, wide sulfur resistance range, and shortens the process flow Effect
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Embodiment 1
[0046] Preparation of catalyst for sulfur-tolerant methanation of syngas in slurry bed:
[0047] 60-80 mesh, specific surface area 150m 2 / g γ-Al 2 o 3 Calcined at 400°C for 4h, at a temperature of 25°C and a stirring speed of 100r / min, the Mo(NO 3 ) 3 ·5H 2 O, Ni(NO 3 ) 2 ·6H 2 O, γ-Al 2 o 3 According to the mass percentage of Mo: Ni: Al 25%: 15%: 60%, impregnate with equal volume and stir for 8 hours, after standing for 4 hours, evaporate to viscous at 60°C, then put it in an oven to dry at 80°C for 12 hours, and then grind to 60-80 mesh Place in a muffle furnace and bake at 450°C for 4h to obtain a precursor; the volume composition is 15%H 2 and 85%N 2 , in an atmosphere with a flow rate of 80mL / min, using a two-stage temperature program, first raising the temperature to 350°C at 4°C / min, and then raising the temperature to 500°C at 2°C / min for 6 hours to obtain Mo:Ni:Al mass percentage 25% : 15%: 60% Mo-Ni-Al slurry bed synthesis gas sulfur resistant methanatio...
Embodiment 2
[0054] Preparation of catalyst for sulfur-tolerant methanation of syngas in slurry bed:
[0055] 80-100 mesh, specific surface area 200m 2 / g γ-Al 2 o 3 Calcined at 450°C for 5h, at a temperature of 30°C and a stirring speed of 200r / min, the Mo(NO 3 ) 3 ·5H 2 O, W (NO 3 ) 3 ·5H 2 O, Ni(NO 3 ) 2 ·6H 2 O, γ-Al 2 o 3 According to the mass percentage of Mo:W:Ni:Al 25%: 10%: 20%: 45% equal volume impregnation and stirring for 10h, after standing for 5h, evaporate at 70°C to viscous, then put it in an oven for 100°C to dry for 12h, then grind To 80-100 mesh, place in a muffle furnace and bake at 500 ° C for 6 hours to obtain a precursor; the volume composition is 20% H 2 and 80%N 2 , in an atmosphere with a flow rate of 100mL / min, two-stage temperature programming is adopted, firstly the temperature is raised to 350°C at 6°C / min, and then the temperature is raised to 550°C at 3°C / min for constant temperature reduction for 6 hours to obtain the mass of Mo:W:Ni:Al Perce...
Embodiment 3
[0062] Preparation of catalyst for sulfur-tolerant methanation of syngas in slurry bed:
[0063] 120-140 mesh, specific surface area 240m 2 / g SiO 2 Calcined at 500°C for 6h, at a temperature of 50°C and a stirring speed of 240r / min, the Mo(NO 3 ) 3 ·5H 2 O, Ce 2 (SO 4 ) 3 ·8H 2 O, Ni(NO 3 ) 2 ·6H 2 O, SiO 2 According to the mass percentage of Mo: Ce: Ni: Si 15%: 15%: 30%: 40% equal volume impregnation and stirring for 24 hours, after standing for 8 hours, evaporate at 90°C until viscous, then put it in an oven for 24 hours at 130°C, and then grind To 120-140 mesh, place in a muffle furnace and bake at 600 ° C for 5 hours to obtain a precursor; the volume composition is 25% H 2 and 75%N 2 , in an atmosphere with a flow rate of 180mL / min, using a two-stage temperature program, first raising the temperature to 350°C at 8°C / min, and then raising the temperature to 600°C at 3°C / min for 10 hours to obtain the mass of Mo:Ce:Ni:Si Percentages 15%: 15%: 30%: 40% Mo-Ce-Ni...
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