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Microalloying AZ91 magnesium alloy with high strength and proper solderability and preparation method thereof

A technology of micro-alloying and AZ91, which is applied in the field of high-strength weldable magnesium alloy and its preparation, high-strength weldable micro-alloyed AZ91 magnesium alloy and its preparation, can solve the problems of high alloy content, reduced mechanical properties of materials, and low welding performance. problems, to achieve the effects of simple process, improved mechanical properties and welding performance, and convenient operation

Inactive Publication Date: 2014-12-24
HUNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The mass percentage composition of AZ91 magnesium alloy is Al8.3-9.3, Zn0.35-1.0, Mn0.15-0.50, Si17 Al 12 , in the process of welding, it is easy to produce liquefaction cracks, and it is impossible to avoid the occurrence of such cracks by improving the welding process
In the industry, the welding performance of AlZ91 series magnesium alloys is usually improved by improving the material composition. However, the AZ91 magnesium alloy itself has a high alloy content, and further addition of alloy elements will reduce the mechanical properties of the material. If excessive rare earth elements are added, they cannot be solid-solved into the matrix. Therefore, there are certain bottlenecks and limitations in improving the mechanical properties of AZ91 magnesium alloy by simply adding alloy elements and rare earth elements.

Method used

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  • Microalloying AZ91 magnesium alloy with high strength and proper solderability and preparation method thereof
  • Microalloying AZ91 magnesium alloy with high strength and proper solderability and preparation method thereof
  • Microalloying AZ91 magnesium alloy with high strength and proper solderability and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] According to the composition ratio of magnesium alloy:

[0030] Al

Zn

mn

Si

Ca

Y

Mg

9

0.6

0.3

0.1

0.1

0.3

margin.

[0031] Take industrially pure Mg (99.9%), pure Al (99.5%), pure Zn (99.9%), Mg-20% Ca, Mg-25.63% Y and elemental Si respectively, and melt them in a crucible in a resistance furnace. Before smelting, all the tools need to be dried first. During the smelting process, the (RJ-2) flux produced by Lianyungang Jingsheng New Material Co., Ltd. is used as the covering agent and refining agent. The melting temperature is 750°C. Add Mg block, after the Mg block is melted, add Zn, Al, Mn, Si in turn, in order to prevent the master alloy from burning, finally add the master alloy Mg-20%Ca and Mg-25.63%Y, after adding all the raw materials, the melt Stand still for 15 minutes, refine for 5 minutes, and finally stand still for 15 minutes. After the slag and melt are separated, cast. 2 Atmosphere p...

Embodiment 2

[0042] According to the composition ratio of magnesium alloy:

[0043] Al

Zn

mn

Si

Ca

Y

Mg

9

0.6

0.3

0.1

0.2

0.4

margin.

[0044] Take industrially pure Mg (99.9%), pure Al (99.5%), pure Zn (99.9%), Mg-20% Ca, Mg-25.63% Y and elemental Si respectively, and melt them in a crucible in a resistance furnace. Before smelting, all the tools need to be dried first. During the smelting process, the (RJ-2) flux produced by Lianyungang Jingsheng New Material Co., Ltd. is used as the covering agent and refining agent. The melting temperature is 750°C. Add Mg block, after the Mg block is melted, add Zn, Al, Mn, Si in turn, in order to prevent the master alloy from burning, finally add the master alloy Mg-20%Ca and Mg-25.63%Y, after adding all the raw materials, the melt Stand still for 15 minutes, refine for 5 minutes, and finally stand still for 15 minutes. After the slag and melt are separated, cast. 2 Atmosphere p...

Embodiment 3

[0055] According to the composition ratio of magnesium alloy:

[0056] Al

Zn

mn

Si

Ca

Y

Mg

9

0.6

0.3

0.1

0.3

0.5

margin.

[0057] Take industrially pure Mg (99.9%), pure Al (99.5%), pure Zn (99.9%), Mg-20% Ca, Mg-25.63% Y and elemental Si respectively, and melt them in a crucible in a resistance furnace. Before smelting, all the tools need to be dried first. During the smelting process, the (RJ-2) flux produced by Lianyungang Jingsheng New Material Co., Ltd. is used as the covering agent and refining agent. The melting temperature is 750°C. Add Mg block, after the Mg block is melted, add Zn, Al, Mn, Si in turn, in order to prevent the master alloy from burning, finally add the master alloy Mg-20%Ca and Mg-25.63%Y, after adding all the raw materials, the melt Stand still for 15 minutes, refine for 5 minutes, and finally stand still for 15 minutes. After the slag and melt are separated, cast. 2 Atmosphere p...

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Abstract

The invention discloses a microalloying AZ91 magnesium alloy with high strength and proper solderability and a preparation method thereof, and the alloy is added with Ca and Y to perform AZ91 magnesium alloy microalloying, wherein the preparation method comprises the following steps of: respectively taking fine metal of Mg, Al and Zn, elemental Si, Mg-Ca, Mg-Y intermediate alloy, and a RJ-2 fusing agent as covering agents and refining agents for smelting according to the component proportion of the designed magnesium alloy, and casting under protective atmosphere; preparing into cast ingots, homogenizing the cast ingots, and performing first deformation of 75-80% and hot rolling deformation at the deformation rate of 9.0-1-9.2-1, and preparing into the AZ91 magnesium alloy with high strength and proper solderability. The preparation method is simple and convenient to operate, by microalloying and high strain deformation, mechanical and welding properties of the AZ91 magnesium alloy can be greatly improved; thus a feasible way is provided to prepare a superfine grain magnesium alloy sheet with high strength and proper solderability.

Description

technical field [0001] The invention relates to a high-strength weldability magnesium alloy and a preparation method thereof, in particular to a high-strength weldability microalloyed AZ91 magnesium alloy and a preparation method thereof, belonging to the technical field of magnesium alloy preparation. Background technique [0002] The mass percentage composition of AZ91 magnesium alloy is Al8.3-9.3, Zn0.35-1.0, Mn0.15-0.50, Si<0.01, Cu<0.03, Ni<0.002, Fe<0.005, and the balance is Mg; its application The range is very wide, but its welding performance is low, because AZ91 magnesium alloy contains a large amount of second phase β-Mg with low melting point 17 Al 12 , In the process of welding, liquefaction cracks are prone to occur, and the occurrence of such cracks cannot be avoided by improving the welding process. In the industry, the welding performance of AlZ91 series magnesium alloys is usually improved by improving the material composition. However, the AZ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C23/02C22C1/03C22C1/06C22F1/06
Inventor 沈言锦严红革
Owner HUNAN UNIV