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A preparation method of carbon nanotube composite bismuth molybdate green deep water treatment agent

A technology of compounding bismuth molybdate and carbon nanotubes is applied in the fields of adsorption water/sewage treatment, oxidized water/sewage treatment, chemical instruments and methods, etc. Inexpensive, strong adsorption effect

Inactive Publication Date: 2016-11-16
DONGHUA UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The methods currently used to treat wastewater mainly include: physical separation, biodegradation, and chemical decomposition, but these methods have certain limitations and are not conducive to sustainable development.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) 10g of carbon nanotubes in 4L of H with a volume ratio of 1:1 2 SO 4 and HNO 3 The mixture was ultrasonically reacted at room temperature for 30 minutes, washed with water until neutral, and vacuum-dried at room temperature for 48 hours to obtain 5 g of carboxylated carbon nanotubes; then the above 5 g of carboxylated carbon nanotubes were dispersed in excess diethylenetriamine, and 100 mg of 2-( 7-azobenzotriazole)-N,N,N',N'-tetramethyluronium hexafluorophosphate, reacted at 40°C for 5h, washed with ethanol, and dried in vacuum at room temperature for 48h to obtain 4g of aminated carbon nano tube; finally ultrasonically disperse 4g of aminated carbon nanotubes in 1L of a mixture of water and acetone with a volume ratio of 3:1, adjust the pH value to 5 with sodium carbonate solution, add 4g of 2,4,6- Trifluoro-5-chloropyrimidine, adjusted the pH value to 6 with sodium carbonate solution, ultrasonically reacted at 20°C for 24h, washed with ethanol, washed with wate...

Embodiment 2

[0033] (1) 10g of carbon nanotubes in 4L of H with a volume ratio of 3:1 2 SO 4 and HNO 3 Ultrasonic reaction at room temperature in the mixed solution for 45 minutes, washed with water until neutral, and vacuum-dried at room temperature for 54 hours to obtain 6.5 g of carboxylated carbon nanotubes; then disperse the above 5 g of carboxylated carbon nanotubes into excess diethylenetriamine, add 300 mg of 2- (7-Azobenzotriazole)-N,N,N',N'-tetramethyluronium hexafluorophosphate, reacted at 45°C for 5h, washed with ethanol, and dried in vacuum at room temperature for 48h to obtain 4.2g of aminated Carbon nanotubes; finally, ultrasonically disperse 4.2g of aminated carbon nanotubes in 1L of a mixture of water and acetone at a volume ratio of 4:1, adjust the pH value to 5.5 with sodium carbonate solution, and add 5g of 2,4 dropwise in an ice-water bath , 6-trifluoro-5-chloropyrimidine, adjust the pH value to 6.2 with sodium carbonate solution, ultrasonically react at 25°C for 36h...

Embodiment 3

[0037] (1) 10g of carbon nanotubes in 4L of H with a volume ratio of 5:1 2 SO 4 and HNO 3 The mixture was ultrasonically reacted at room temperature for 60 minutes, washed with water to neutrality, and vacuum-dried at room temperature for 60 hours to obtain 8 g of carboxylated carbon nanotubes; then the above 8 g of carboxylated carbon nanotubes were dispersed in excess diethylenetriamine, and 600 mg of 2-( 7-azobenzotriazole)-N,N,N',N'-tetramethyluronium hexafluorophosphate, reacted at 50°C for 5h, washed with ethanol, and dried in vacuum at room temperature for 48h to obtain 4.5g of carbon amides nanotubes; finally ultrasonically disperse 4.5g of aminated carbon nanotubes in 1L of a mixture of water and acetone at a volume ratio of 5:1, adjust the pH value to 6 with sodium carbonate solution, add 6g of 2,4, 6-trifluoro-5-chloropyrimidine, adjust the pH value to 6.5 with sodium carbonate solution, ultrasonically react at 30°C for 48h, wash with ethanol, wash with water, dry...

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Abstract

The invention relates to a preparation method of a carbon nano tube composite bismuth molybdate environmentally friendly and deep water treatment agent. The preparation method comprises the following steps: (1), carboxylation and amination modification are performed on a carbon nano tube and 2,4,6-trifluoro-5-chloro-pyrimidine is modified to prepare a reaction type carbon nano tube; (2), bismuth salt, a stabilizer, a template agent and the reaction type carbon nano tube are added into a phosphate buffer solution, and stirring is performed for 30 to 60 min, so as to form turbid liquid; molybdate is dissolved into the phosphate buffer solution, and then the phosphate buffer solution is added into the turbid liquid, so as to form a transparent solution; (3), the product is obtained after filtering and drying. The preparation method provided by the invention has the advantages that the cost is low, the preparation method is simple, requirements for equipment are low, and the maneuverability is excellent; the water treatment agent can be used for removing high concentration organic pollutants in water, is suitable for deep treatment on various wastewater, environmental protection and zero secondary pollution are achieved, and the water treatment agent is antibacterial, deodorant and can absorb other heavy metal ions and the like.

Description

technical field [0001] The invention belongs to the field of water treatment agents, in particular to a preparation method of a carbon nanotube composite bismuth molybdate green deep water treatment agent. Background technique [0002] Only about 10% of the world's water is directly used by humans. The largest share, 70%, is used in agriculture, and the remaining 20% ​​is used in industry. China's sewage is about 20% of the world's, but it only gets 5% of the world's fresh water. Therefore, solving the pollution problem is on the agenda. In the process of textile printing and dyeing, leather, and paper-making industries, a large number of additives that pollute the environment and are harmful to the human body are used. Most of these additives are discharged in the form of liquid and pollute the environment. They have poor biodegradability, high toxicity, and high free formaldehyde content. The content of heavy metal ions exceeds the standard. Among them, printing and dy...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/652C02F1/28C02F1/72
Inventor 刘保江高品王炜
Owner DONGHUA UNIV
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