Adjustment method of gradient delay volume
A volume adjustment and gradient delay technology, applied in the field of high performance liquid chromatography, which can solve the problems of high cost and inconvenience
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[0039] Such as figure 1 The graph shown shows how the change in GDV affects the analysis with respect to time at the (sample) injection at time 0 minutes. In the graph, the solvent composition is represented by a dotted line with respect to time. Solvent composition (several transitions in the form of inflection points) from a constant (lower or front horizontal section) lower limit (40% acetonitrile) through a changing (from 40% to 70% acetonitrile) composition or gradient (ascending linear central region) Change to a constant (upper or rear horizontal fraction) upper limit (acetonitrile 70%). As a gradient, for example, a gradient of increasing solvent component B, eg acetonitrile CAN, from 40% to 70% in 16 seconds (and a corresponding decrease of solvent component A or from 60% to 30% of the remaining solvent components) is used. In the upper graph (case A), the preset pump volume V of the volume regulator A = 25 μL, i.e., GDV increased by 25 μL, while in the lower graph...
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