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A titanium dioxide-diatom mud composite material method for indoor photocatalytic degradation of formaldehyde prepared by biological template

A biological template, catalytic degradation technology, applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve problems such as difficulty in recycling

Active Publication Date: 2018-08-31
YUNNAN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] Therefore, we consider loading TiO2 prepared by a biological template on the treated diatomite surface. 2 The photocatalyst can not only increase the contact area between the light-receiving area receiving ultraviolet rays and the substrate, but also improve the TiO 2 Excellent photocatalytic activity, overcome the shortcomings of single suspension phase photocatalytic system, such as difficult recovery and easy aggregation

Method used

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  • A titanium dioxide-diatom mud composite material method for indoor photocatalytic degradation of formaldehyde prepared by biological template
  • A titanium dioxide-diatom mud composite material method for indoor photocatalytic degradation of formaldehyde prepared by biological template
  • A titanium dioxide-diatom mud composite material method for indoor photocatalytic degradation of formaldehyde prepared by biological template

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Take 1000g of diatomite ore, add 1500mL of water and 5g of sodium hydroxide, stir and disperse for 30 minutes with a stirrer in the laboratory, and separate impurities such as grass roots and bark with a 50-mesh sieve; then the obtained product is gravity settled overnight in a plastic basin, and then The ore pulp was separated by a sedimentation centrifuge for 15 minutes, stirred at 90°C for 4 hours, filtered and washed; then roasted at 600°C for 4 hours. Choose diatomaceous earth.

[0045] Take fresh cattails, wash them, remove dead leaves, and check out fresh plants, leaves and roots. Take out the washed stems and cut them into pieces of a certain size, about 1000g. And first soak overnight with 2.5% glutaraldehyde, then soak with 5% HCl, and finally use 30%, 60%, 90%, 100% ethanol to carry out gradient dehydration, and the amount of ethanol used each time should be enough to completely submerge Templates are better. Add Ti precursor solution (TTIP: ethanol: acety...

Embodiment 2

[0048] Take 1000g of diatomite ore, add 1500mL of water and 5g of sodium hydroxide, stir and disperse for 30 minutes with a stirrer in the laboratory, and separate impurities such as grass roots and bark with a 50-mesh sieve; then the obtained product is gravity settled overnight in a plastic basin, and then The ore pulp was separated by a sedimentation centrifuge for 15 minutes, stirred at 90°C for 4 hours, filtered and washed; then roasted at 600°C for 4 hours. Choose diatomaceous earth.

[0049] Take fresh cattails, wash them, remove dead leaves, and check out fresh plants, leaves and roots. Take out the washed roots and cut them into pieces of a certain size, about 1000g. And first soak overnight with 2.5% glutaraldehyde, then soak with 5% HCl, and finally use 30%, 60%, 90%, 100% ethanol to carry out gradient dehydration, and the amount of ethanol used each time should be enough to completely submerge Templates are better. Add Ti precursor solution (TTIP: ethanol: acety...

Embodiment 3

[0052] Take 1000g of diatomite ore, add 1500mL of water and 5g of sodium hydroxide, stir and disperse for 30 minutes with a stirrer in the laboratory, and separate impurities such as grass roots and bark with a 50-mesh sieve; then the obtained product is gravity settled overnight in a plastic basin, and then The ore pulp was separated by a sedimentation centrifuge for 15 minutes, stirred at 90°C for 4 hours, filtered and washed; then roasted at 600°C for 4 hours. Choose diatomaceous earth.

[0053] Take fresh cattails, wash them, remove dead leaves, and check out fresh plants, leaves and roots. Take out the washed leaves and cut them into pieces of a certain size, about 1000g. And first soak overnight with 2.5% glutaraldehyde, then soak with 5% HCl, and finally use 30%, 60%, 90%, 100% ethanol to carry out gradient dehydration, and the amount of ethanol used each time should be enough to completely submerge Templates are better. Add Ti precursor solution (TTIP: ethanol: acet...

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Abstract

The invention relates to a method for preparing a photocatalyst-loaded titanium dioxide-diatom ooze composite material for indoor photocatalytic degradation of formaldehyde by a biological template, and belongs to the technical field of photocatalysis paint. The method comprises keeping morphology of cattail leaves as templates by a reagent method, adding a titanium precursor into the treated templates for a reaction, drying and calcining the products, carrying out grinding to obtain cattail leaf-titanium dioxide, simultaneously, carrying out fine treatment on diatomite raw ore to obtain refined diatomite, and then carrying out further fine treatment on the refined diatomite and the cattail leaf-titanium dioxide to obtain the nanometer titanium dioxide-loaded diatom ooze which is prepared by a biological template and is used for high efficiency adsorption of inner formaldehyde. The method has simple processes. The titanium dioxide-diatom ooze composite material has high efficiency photocatalytic degradation activity of the adsorbed formaldehyde.

Description

technical field [0001] The invention relates to a kind of coating—TiO2, which is used for degrading indoor formaldehyde, is prepared from a biological template, and is loaded with a photocatalyst. 2 -The preparation method of the diatom ooze composite material belongs to the technical field of photocatalytic coating. Background technique [0002] Excessive formaldehyde concentration can cause acute poisoning, manifested as burning throat, dyspnea, pulmonary edema, allergic purpura, allergic dermatitis, elevated liver transaminase, jaundice, etc. Formaldehyde, which is harmful to the human body in daily life, can be said to be everywhere. The items involved include furniture, wooden floors; children's clothing, non-ironing shirts; fast food noodles, rice noodles; blistered squid, sea cucumbers, beef louvers, shrimps; and even cars. It is not difficult to see that formaldehyde has been involved in all four of the most important things in our lives—clothing, food, housing, an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J21/16B01D53/86B01D53/72
Inventor 王家强李懿舟袁发贵段德良王伟闫智英陈永娟和佼毕银章
Owner YUNNAN UNIV