A kind of high temperature resistant phosphate transparent glass and its preparation method
A technology of transparent glass and phosphate, applied in the field of phosphate transparent glass and its preparation, can solve the problems of uneven mixed powder, easy to produce phase separation, easy to produce air bubbles, etc. The effect of dense structure
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Embodiment 1
[0049] According to the mass parts, 1 part of MgO, 4 parts of water, mixed, ball milled for 25 minutes, mixed with 30 parts of aluminum dihydrogen phosphate aqueous solution, 48.81 parts of aluminum monohydrogen phosphate aqueous solution, wherein the mass content of the solute in the phosphate aqueous solution is 60%. The speed of adding phosphate to the MgO suspension is 0.7g / min, and magnetically stirred for 2.5h. Dry in an oven at 290°C for 10h, grind, sieve powder, the hole diameter is 0.25mm, press molding at 100MPa, keep at 1500°C for 1h20min, and sinter into transparent glass. Solute in MgO / phosphate aqueous solution = 2.11%.
Embodiment 2
[0051] According to the mass parts, 1 part of MgO, 4 parts of water, mixed, ball milled for 35 minutes, mixed with 20 parts of aluminum dihydrogen phosphate aqueous solution and 79.56 parts of aluminum monohydrogen phosphate aqueous solution, wherein the mass content of the solute in the phosphate aqueous solution is 45%. The speed of adding phosphate to the MgO suspension is 0.65g / min, and magnetically stirred for 2.5h. Dry in an oven at 290°C for 10h, grind, sieve powder, the aperture is 0.15mm, press at 75MPa, hold at 1500°C for 1h40min, and sinter into transparent glass. Solute in MgO / phosphate aqueous solution = 2.23%.
Embodiment 3
[0053] According to the mass parts, 1 part of MgO, 4 parts of water, mixed, ball milled for 35 minutes, mixed with 5 parts of aluminum dihydrogen phosphate aqueous solution, 23.18 parts of aluminum monohydrogen phosphate aqueous solution, wherein the mass content of the solute in the phosphate aqueous solution is 50%. The speed of adding phosphate to the MgO suspension is 0.8g / min, and magnetically stirred for 3h. Dry in an oven at 275°C for 8 hours, grind, sieve powder, the hole diameter is 0.18mm, press at 95MPa, hold at 1500°C for 30min, and sinter into transparent glass. Solute in MgO / phosphate aqueous solution = 7.10%.
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