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Polyglyceryl polyether polyol and preparation method thereof

A technology of polyether polyol and polymerized glycerin is applied in the field of polymerized glyceryl polyether polyol and its preparation, and achieves the effects of less pollution, simple synthesis method and convenient operation.

Active Publication Date: 2017-07-14
SHANDONG INOV NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the commonly used rubber internal mold release agents on the market often use emulsified silicone oils, and there are very few reports involving polymerized glyceryl polyethers.

Method used

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  • Polyglyceryl polyether polyol and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] In a 5L autoclave equipped with a stirrer, a meter, a heating temperature control device, a cooling device (including an outer jacket and an inner coil) and a pressure sensor, add 362 g of tetrapolyglycerol, 5.5 g of potassium hydroxide, and replace with nitrogen for 5 times After adding 135g of ethylene oxide, heat up and stir, and react at 80-85°C with a pressure of 0.25MPa for 2 hours. Afterwards, the temperature was raised to 115°C, and the pressure was controlled at 0.25MPa. The remaining 2013g of ethylene oxide was divided into 10 batches and added successively. After the addition was completed, the reaction was carried out, and the post-aging was performed for 4 hours. After that, a phosphoric acid aqueous solution was added to neutralize the reaction at 100°C. After 1 hour, add 1.5g of magnesium silicate and 1.5g of aluminum silicate, stir thoroughly for 20 minutes, dehydrate under vacuum, filter, add antioxidant Chic 3338: 1.5g, ChicF96: 3.0g to the obtained pol...

Embodiment 2

[0028] In a 5L autoclave equipped with a stirrer, a meter, a heating temperature control device, a cooling device (including an outer jacket and an inner coil) and a pressure sensor, add 100 g of triglycerol, 150 g of tetraglycerol, 110 g of pentaglycerol, Potassium hydroxide 6.5g, nitrogen replacement 3 times, add 190g propylene oxide, heat up and stir, react at 80-85°C, pressure 0.2MPa for 2 hours. Afterwards, the temperature was raised to 110°C, the pressure was controlled at 0.3MPa, and the remaining 2650g of propylene oxide was divided into 8 batches and added successively. After the addition was completed, the reaction was carried out, and after aging for 5 hours, the phosphoric acid aqueous solution neutralizing agent was added to carry out the neutralization reaction at 95°C. After 2 hours, add 3.3g of magnesium silicate and 2.3g of aluminum silicate, stir well for 20 minutes, dehydrate and filter under vacuum, add antioxidant Chic3338: 5.0g, Chic F96: 2.5g to the obtai...

Embodiment 3

[0030] In a 5L autoclave equipped with a stirrer, a meter, a heating temperature control device, a cooling device (including an outer jacket and an inner coil) and a pressure sensor, add 350 g of tetraglycerol, 120 g of pentaglycerol, and 8 g of potassium hydroxide, Nitrogen was replaced 4 times, 90g of butylene oxide was added, heated and stirred, and reacted at 80-85°C and pressure 0.3MPa for 2 hours. Afterwards, the temperature was raised to 115°C, and the pressure was controlled at 0.3MPa. The remaining 1558g of propylene oxide was divided into 9 batches and added successively. After the addition was completed, the reaction was carried out, and the post-aging was performed for 6 hours. After that, a phosphoric acid aqueous solution was added to neutralize the reaction at 95°C. 1 hour, add 3g of magnesium silicate and 4.5g of aluminum silicate, stir well for 20 minutes, dehydrate and filter under vacuum, add antioxidant Chic 3338: 3.0g, ChicF96: 3.0g to the obtained polyethe...

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Abstract

The invention belongs to the technical field of chemical synthesis, and particularly relates to polyglycerol polyether polyol and a preparation method thereof. The polyglycerol polyether polyol is prepared from, by weight, 300-500 parts of initiator, 1500-3000 parts of oxyalkylene, 5-10 parts of catalyst, 8-20 parts of neutralizer, 2-8 parts of adsorbent and 10-20 parts of compound additives. According to the polyglycerol polyether polyol and the preparation method thereof, the raw materials are easy to obtain, pollution is less, the synthetic method is simple, and operation is convenient.

Description

technical field [0001] The invention belongs to the technical field of chemical synthesis, and in particular relates to a polymerized glyceryl polyether polyol and a preparation method thereof. Background technique [0002] Currently commercially available polyether polyol products often use sucrose, sorbitol, propylene glycol, glycerin, etc. as initiators, among which the initiators with higher functionality are mainly sucrose, sorbitol, etc. Few products involve the use of polymerized glycerol as the main starting system. [0003] Polyglycerin has higher viscosity and boiling point than glycerin, less volatility and hygroscopicity, good moisture retention, and has the characteristics of improving emulsification stability, so it is often used in cosmetics, fiber industry, plastic industry and other fields, but as an initiator preparation There are basically no reports on polyethers. [0004] The polyether polyol product prepared by using polyglycerin as the main starting ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G65/28C08G65/30
Inventor 刘军宁晓龙马海晶念以亭
Owner SHANDONG INOV NEW MATERIALS CO LTD