Preparation method of high-temperature-resistant polyethylene fiber and rubber composite

A high-temperature-resistant polyethylene and polyethylene fiber technology, which is applied in the field of preparation of high-temperature-resistant polyethylene fiber rubber composite materials, can solve problems such as poor tensile properties and compression resistance, polyethylene fibers are not resistant to high temperatures, and surface processing is difficult , to achieve the effect of high flexibility and good compression resistance

Inactive Publication Date: 2016-02-24
高大元
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problems mainly solved by the present invention are as follows: polyethylene fibers are not resistant to high temperature, surface processing is difficult, difficult to dye, difficult to bond with other materials, poor creep resistance, poor tensile and compression resistance of general rubber, and in Under wet conditions, the tear performance and puncture resistance of rubber are poor. A preparation method for high temperature resistant polyethylene fiber rubber composite material is provided. The invention uses ultra-high molecular weight polyethylene fiber to prepare polyethylene fiber semi-diluted solution, put it into a plasma generating device for surface modification to obtain a semi-dilute solution of modified polyethylene fiber, mix it with silica sol prepared from ethyl silicate and absolute ethanol, etc., to obtain polyethylene fiber dioxide Silicon mixed solution, take natural rubber, add zinc oxide and stearic acid cutter, pour polyethylene fiber silicon dioxide mixed solution, add accelerator, etc., knead, dry and crush to obtain a high temperature resistant polyethylene fiber Rubber composite material, the invention utilizes the characteristics of high flexibility, high elasticity and relatively strong fiber rigidity of rubber to effectively combine the characteristics of the two. The performance of the composite material is better than that of traditional rubber products, not only high temperature resistance, but also tensile strength. Good tensile and compression resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0018] First weigh 200g of ultra-high molecular weight polyethylene fiber and put it into a 2L beaker, add 500mL of kerosene, place it on a magnetic stirrer, stir at a speed of 400r / min until the polyethylene fiber is completely dissolved, and obtain a semi-dilute solution of polyethylene fiber; Put the semi-dilute polyethylene solution into the plasma generator, start the device, make it in the plasma atmosphere, carry out the surface modification for 5 minutes, the treatment power is 1000W, after the modification is completed, take it out and let it stand at 30°C for 2 hours to obtain the modified polymer. Ethylene fiber semi-dilute solution; measure 15mL ethyl silicate and 10mL absolute ethanol into a 200mL beaker, stir evenly with a glass rod, then place it on a magnetic stirrer, set the speed at 200r / min, and stir slowly in order Add 10 mL of ethanol solution with a mass concentration of 80%, 15 mL of deionized water and 1 mL of hydrochloric acid solution with a mass conce...

example 2

[0021]First weigh 250g ultra-high molecular weight polyethylene fiber and put it into a 2L beaker, add 550mL kerosene, place it on a magnetic stirrer, stir until the polyethylene fiber is completely dissolved at a speed of 450r / min, and obtain a semi-dilute solution of polyethylene fiber; Put the semi-dilute polyethylene solution into the plasma generating device, start the device, make it in the plasma atmosphere, carry out the surface modification for 8 minutes, and the processing power is 1300W. Vinyl fiber semi-dilute solution; measure 18mL ethyl silicate and 13mL absolute ethanol into a 200mL beaker, stir evenly with a glass rod, then place it on a magnetic stirrer, set the speed at 250r / min, and stir slowly in order Add dropwise 13mL of ethanol solution with a mass concentration of 80%, 18mL of deionized water and 1mL of a hydrochloric acid solution with a mass concentration of 30%, and continue stirring for 35min to obtain a silica sol; measure 450mL of the semi-dilute s...

example 3

[0024] First weigh 300g of ultra-high molecular weight polyethylene fiber and put it into a 2L beaker, add 600mL of kerosene, place it on a magnetic stirrer, stir at a speed of 500r / min until the polyethylene fiber is completely dissolved, and obtain a semi-dilute solution of polyethylene fiber; Put the semi-dilute polyethylene solution into the plasma generator, start the device, make it in the plasma atmosphere, carry out the surface modification for 10 minutes, the treatment power is 1500W, take it out after the modification and let it stand at 40°C for 3 hours to obtain the modified poly Ethylene fiber semi-dilute solution; measure 20mL ethyl silicate and 15mL absolute ethanol into a 200mL beaker, stir evenly with a glass rod, then place it on a magnetic stirrer, set the speed at 300r / min, and slowly stir in order Add 15mL of ethanol solution with a mass concentration of 80%, 20mL of deionized water and 2mL of hydrochloric acid solution with a mass concentration of 30%, and...

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PUM

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Abstract

The invention discloses a preparation method of high-temperature-resistant polyethylene fiber and rubber composite and belongs to the field of composite. A polyethylene fiber semi-dilute solution is prepared from ultra-high molecular weight polyethylene fiber and put in a plasma generating device for surface modification, a modified polyethylene fiber semi-dilute solution is prepared and mixed with silica sol prepared from ethyl silicate, absolute ethyl alcohol and the like, a polyethylene fiber and silica mixed solution is obtained, natural rubber is taken, zinc oxide and stearic acid are added, the mixture is cut by a cutter, the polyethylene fiber and silica mixed solution, an accelerator and the like are added, the mixture is mixed, dried and smashed, and the high-temperature-resistant polyethylene fiber and rubber composite is obtained. The characteristics of high rubber flexibility, high elasticity and higher fiber rigidity are used, characteristics of polyethylene fiber and rubber are effectively combined, the performance of the composite is superior to that of a conventional rubber product, and the composite is resistant to high temperature and has good stretching performance and compression resistance.

Description

technical field [0001] The invention discloses a preparation method of a high-temperature-resistant polyethylene fiber rubber composite material, which belongs to the field of composite materials. Background technique [0002] Ultra-high molecular weight polyethylene fiber is a high-performance fiber developed since the 1980s. It is a representative product of gel spinning technology using gel spinning super stretching technology in industrial production. The traditional cross-linking methods are radiation cross-linking and thermochemical cross-linking, but these two cross-linking methods will damage the mechanical properties of the fiber. High-energy radiation will break the molecular chain of the fiber, and the fiber strength will decrease with the increase of the radiation dose. . Thermochemical crosslinking is to generate crosslinking through the thermal decomposition of the initiator at high temperature, which will cause the highly oriented macromolecular chains to rel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L7/00C08K13/02C08K3/36C08K3/22C08K5/09C08K5/405C08K5/39
CPCC08L23/06C08L2201/08C08L7/00C08K13/02C08K3/36C08K2003/2296C08K5/09C08K5/405C08K5/39
Inventor 高大元林大伟王志慧
Owner 高大元
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