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Chemically strengthened glass and method for producing chemically strengthened glass

A technology for strengthening glass and manufacturing method, applied in the field of chemical strengthening glass, can solve problems such as difficult strengthening treatment, and achieve the effect of realizing cost

Active Publication Date: 2018-04-10
AGC INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In general, in chemically strengthened glass, it is difficult to perform strengthening treatment because K ions cannot diffuse into the glass after forming an anti-reflection film.

Method used

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  • Chemically strengthened glass and method for producing chemically strengthened glass
  • Chemically strengthened glass and method for producing chemically strengthened glass
  • Chemically strengthened glass and method for producing chemically strengthened glass

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0184] 2,568 g of potassium nitrate, 321 g of potassium carbonate, and 111 g of sodium nitrate were added to a cup made of stainless steel (SUS), and heated to 450° C. with a hooded heater to prepare a molten salt with 8 mol % of potassium carbonate and a Na concentration of 10,000 ppm by weight. . Use a stirring motor and 4 propeller blades to stir the prepared molten salt for 2 hours, so that the whole is uniformly mixed.

[0185] The aluminosilicate glass of 50 mm x 50 mm x 0.7 mm was preheated to 200° C. to 400° C., and then immersed in molten salt at 450° C. for 2 hours to perform chemical strengthening treatment. After strengthening treatment, the glass was washed twice with ion-exchanged water at 50°C to 90°C, washed with running water at room temperature, and dried at 60°C for 2 hours.

[0186] Various physical properties of the obtained glass were measured, and D1 / D3 and C1 were calculated. Table 2 shows the measurement results and calculation results.

Embodiment 2、12

[0188]402 g of potassium nitrate and 47.9 g of potassium carbonate were added to a cup made of SUS, and heated to 450° C. with a mantle heater to prepare a molten salt of 8 mol % of potassium carbonate. Use a stirring motor and 4 propeller blades to stir the prepared molten salt for 2 hours, so that the whole is evenly mixed.

[0189] Aluminosilicate glass (Example 2) or soda lime glass (Example 12) was strengthened, washed and dried in the same manner as in Example 1, and then acid-treated in the following procedure.

[0190] 1 mol / L (1M) hydrochloric acid was prepared in a beaker, and the temperature was adjusted to 40° C. using a water bath. The chemically strengthened glass was acid-treated by immersing it in prepared hydrochloric acid for 5 minutes, washed three times with ion-exchanged water, and then dried at 60° C. for 2 hours.

[0191] Various physical properties of the obtained glass were measured, and D1 / D3 was calculated. Table 2 shows the measurement results and...

Embodiment 3

[0193] The aluminosilicate glass was tempered, washed, and dried in the same manner as in Example 1, and then acid-treated in the same manner as in Example 2.

[0194] Various physical properties of the obtained glass were measured, and D1 / D3 and C1 were calculated. Table 2 shows the measurement results and calculation results.

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Abstract

The present invention relates to a chemically strengthened glass having a compressive stress layer formed by ion exchange on a glass surface, wherein the chemically strengthened glass has a low density layer formed by reducing the density of the surface of the compressive stress layer, The thickness of the low-density layer is 5 nm to 200 nm, and the ratio of the density (D1) of the low-density layer to the density (D3) of the intermediate layer present in the center of the glass and sandwiched between the compressive stress layers (D1 / D3) is 0.5 or more and less than 0.93.

Description

technical field [0001] The present invention relates to a novel chemically strengthened glass and a method for producing the chemically strengthened glass. Background technique [0002] Glass that has been chemically strengthened by ion exchange or the like is used for the cover glass of display devices such as digital cameras, mobile phones, and PDAs (Personal Digital Assistants) and glass substrates for displays (hereinafter, sometimes simply referred to as "chemically strengthened glass"). .). Although the theoretical strength of glass is high, its strength is greatly reduced due to damage. Chemically strengthened glass is suitable for these applications because it has higher mechanical strength than unstrengthened glass and prevents damage to the glass surface. [0003] In addition, in recent years, the number of examples adopted as a cover glass for solar cells has also increased. By replacing the existing protective glass with chemically strengthened glass, the same...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C21/00C03C23/00
CPCC03C3/087C03C21/002C03C23/0075
Inventor 山田拓仁平敏史世良洋一铃木祐一小林大介
Owner AGC INC