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Electrolyte solution of lithium manganate battery used at high temperature

A lithium manganese oxide battery and electrolyte technology, which can be applied to secondary batteries, circuits, electrical components, etc., and can solve the problems of low cost and large-scale application

Inactive Publication Date: 2016-03-23
SHANDONG HONGZHENG BATTERY MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to cost and technical problems, it has not been widely applied

Method used

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  • Electrolyte solution of lithium manganate battery used at high temperature
  • Electrolyte solution of lithium manganate battery used at high temperature
  • Electrolyte solution of lithium manganate battery used at high temperature

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] LiPF6 lithium salt was dissolved in a mixed solvent of ethylene carbonate (EC), ethylmethyl carbonate (EMC), diethyl carbonate (DEC) (mass ratio 3:5:2), wherein the concentration of LiPF6 was 1M. Then add vinylene carbonate (VC), 3% of 1,3-propane sultone (PS), 0.001% of hexamethyldisilazane, 0.5 % added 3,4-difluorosulfolane. well mixed.

Embodiment 2

[0021] Dissolve LiPF6 lithium salt in a mixed solvent of ethylene carbonate (EC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC), propylene carbonate (PC) (mass ratio 3:4:1:1) Among them, the concentration of LiPF6 is 1M. Then add vinylene carbonate (VC), 2% of 1,3-propane sultone (PS), 0.001% of hexamethyldisilazane, 0.5 % added 3,4-difluorosulfolane. well mixed.

Embodiment 3

[0023] Dissolve LiPF6 lithium salt in a mixed solvent of ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), ethyl methyl carbonate (EMC) (mass ratio 4:1:7:4) Among them, the concentration of LiPF6 is 1M. Then add vinylene carbonate (VC), 1% add 1,3-propane sultone (PS), 1% add bisoxalate lithium borate (BOB), 1% by 1% of the total mass of the electrolyte in the electrolyte solution % added fluoroethylene carbonate (FEC), 0.001% added hexamethyldisilazane, 0.5% added 3,4-difluorosulfolane. well mixed.

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Abstract

The invention discloses an electrolyte solution capable of solving the problem of poor high-temperature performance of a lithium manganate battery. The electrolyte solution contains a lithium salt, a non-aqueous organic solvent, various additives and the like, wherein the lithium salt accounts for 15-20% of the electrolyte solution based on the total weight of the electrolyte solution; the non-aqueous organic solvent accounts for 60-80% of the electrolyte solution based on the total weight of the electrolyte solution; the additives account for 8-19% of the electrolyte solution based on the total weight of the electrolyte solution; the additives are preferentially selected from combination of a film-forming additive, a high-temperature additive, an anti-overcharging additive, a flame-retardant additive and a stable additive; and in the additives, the additive amount of the film-forming additive is preferentially 0.2-5%, the additive amount of the high-temperature additive is preferentially 0.2-5%, the additive amount of the anti-overcharging additive is preferentially 0.2-5%, the additive amount of the flame-retardant additive is preferentially 0.2-5%, and the additive amount of the stable additive is preferentially 0.003-3.0%. The electrolyte solution is characterized in that various additives of the electrolyte solution are reasonably designed in component; and a 3,4-difluorosulfolane additive is also added, so that the lithium manganate battery manufactured from the electrolyte solution has excellent high-temperature performance.

Description

technical field [0001] The invention relates to an electrolyte solution for a lithium ion battery, in particular to a nonaqueous electrolyte solution for solving the problem of poor high-temperature performance of a lithium ion battery using lithium manganate as a positive electrode material. Background technique [0002] Over the past 20 years, lithium-ion batteries have been widely used in electronic communication fields such as mobile phones, notebook computers, and digital products, and have occupied a dominant position. Due to problems such as technology and cost, lithium-ion batteries have been stuck in the field of use of small and medium-sized batteries. With the rapid development of lithium-ion battery key material technology and battery technology, large-scale power batteries and battery packs used in vehicles, electric tools, and electric toys have begun to become popular in daily life. Manganese-based cathode materials are considered to be the most promising cat...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/0566
CPCY02E60/10
Inventor 岳蒙蒙谷秀娟姜翠平梁振洋
Owner SHANDONG HONGZHENG BATTERY MATERIAL TECH
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