The invention relates to a method for preparing a
polymer clad
nickel aluminum
alloy /
sulfur composite electrode material. The method is characterized by comprising the steps of: by taking hollow
nickel aluminum
alloy nanometer
powder as a carrier for the
polymer clad
nickel aluminum
alloy /
sulfur composite electrode material, carrying out heating sublimation,
diffusion, and condensation on
sulfur to obtain a nickel aluminum alloy / sulfur
composite material; ultrasonically dispersing the nickel aluminum alloy / sulfur
composite material and a polymeric precursor in an
alcohol-water blend, then adding a catalyst, and carrying out
polymerization, stirring, deposition, filtering, collecting, and
drying to obtain the
polymer clad nickel aluminum alloy / sulfur
composite electrode material, wherein the nickel aluminum alloy is one of
NiAl3 and
NiAl2, sulfur accounts for 30-70% of the total
mass of the polymer clad nickel aluminum alloy / sulfur composite
electrode material, and a polymer accounts for 0.5-10% of the total
mass of the polymer clad nickel aluminum alloy / sulfur composite
electrode material. When used as the positive
electrode for a
lithium sulfur battery, the
composite material has a good specific capacity and excellent
cycling performance, wherein the first
discharge capacity is greater than 500mAh / g, and the
discharge specific capacity
retention rate is greater than 74% after 100 cycles.