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A kind of surface modification method of carbon steel

A surface modification, carbon steel technology, applied in the direction of metal material coating process, coating, solid diffusion coating, etc., can solve the problems of complex process, high cost, difficult operation, etc., to achieve simple process flow, convenient operation, The effect of easy experimental conditions

Inactive Publication Date: 2018-10-26
NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing technology has disadvantages such as complex process, difficult operation, high cost, etc., and the anti-corrosion performance needs to be further improved.

Method used

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  • A kind of surface modification method of carbon steel

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] 1. First, degrease and derust the surface of the carbon steel, then use silicon carbide sandpaper to grind the surface of the carbon steel to 2000 grades, use a knife to carve a line along the vertical line of the long side of the sample, and then pass through high-purity water-ethanol - Rinse and wipe with high-purity water, dry with cold air, and place in a drying oven for later use;

[0030] 2 Configure 0.24mol / L ZnSO4 solution;

[0031] 3 Take a clean sample in a small crucible, add a few drops of 0.24mol / L ZnSO4 solution to the left half of the engraved vertical line, until about 90% of the left half is covered by ZnSO4 solution, and the thickness of the droplet film is about 2mm ;

[0032] 4 Place the above-mentioned treated carbon steel sample in the muffle furnace, control the heating rate at 15-20°C, raise the temperature to 230°C, keep it for 80 minutes, turn off the temperature control switch of the muffle furnace, and cool naturally;

[0033] 5 After the m...

Embodiment 2

[0035] 1. First, degrease and derust the surface of the carbon steel, then use silicon carbide sandpaper to grind the surface of the carbon steel to 2000 grades, use a knife to carve a line along the vertical line of the long side of the sample, and then pass through high-purity water-ethanol - Rinse and wipe with high-purity water, dry with cold air, and place in a drying oven for later use;

[0036] 2 Configure 0.24mol / L ZnSO4 solution;

[0037] 3 Take a clean sample in a small crucible, add a few drops of 0.24mol / L ZnSO4 solution to the left half of the engraved vertical line, until about 90% of the left half is covered by ZnSO4 solution, and the thickness of the droplet film is about 2mm ;

[0038] 4 Place the above-mentioned treated carbon steel sample in the muffle furnace, control the heating rate at 15-20°C, raise the temperature to 240°C, keep it for 70 minutes, turn off the temperature control switch of the muffle furnace, and cool naturally;

[0039] 5 After the m...

Embodiment 3

[0041] 1. First, degrease and derust the surface of the carbon steel, then use silicon carbide sandpaper to grind the surface of the carbon steel to 2000 grades, use a knife to carve a line along the vertical line of the long side of the sample, and then pass through high-purity water-ethanol - Rinse and wipe with high-purity water, dry with cold air, and place in a drying oven for later use;

[0042] 2 Configure 0.24mol / L ZnSO4 solution;

[0043] 3 Take a clean sample in a small crucible, add a few drops of 0.24mol / L ZnSO4 solution to the left half of the engraved vertical line, until about 90% of the left half is covered by ZnSO4 solution, and the thickness of the droplet film is about 2mm ;

[0044] 4 Place the above-mentioned treated carbon steel sample in the muffle furnace, control the heating rate at 15-20°C, raise the temperature to 250°C, keep it warm for 60min, turn off the temperature control switch of the muffle furnace, and cool naturally;

[0045] 5 After the m...

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Abstract

The invention provides a surface modification method for carbon steel. The method comprises the following steps of: step (a), dropwise adding a 0.2-0.3 mol / L ZnSO4 solution on the surface of the carbon steel; and step (b), putting the carbon steel obtained in the step (a) in a muffle furnace, raising the temperature to 230-280 DEG C, insulating for 30-80 minutes, and cooling, washing and drying the carbon steel. Compared with the prior art, the surface modification method for the carbon steel has the features that the ZnSO4 solution is dropwise added on the surface of pre-treated clean carbon steel for high-temperature zincizing by adopting a high-temperature zincizing method. Therefore, the elementary composition of the surface of the carbon steel is changed by surface modification, so that the corrosion resistance of the carbon steel is improved. Through detection by an electrochemical method, the surface of the treated carbon steel contains zinc element, so that the corrosion resistance of the carbon steel is improved. Secondly, the method provided by the invention is simple in process flow, convenient to operate and low in requirements of equipment, and the experimental conditions are easy to achieve. Further, the method provided by the invention is short in preparation time of samples and high in efficiency.

Description

technical field [0001] The invention relates to the technical field of anticorrosion treatment, in particular to a method for modifying the surface of carbon steel. Background technique [0002] Carbon steel is an important material related to the development of the national economy. It is widely used in various heat exchanger components and pipeline equipment due to its rich resources, low price, simple production, and various performances. However, its corrosion failure problem still cannot be ignored. Carbon steel corrosion is a spontaneous metallurgical reverse process. The loss and damage caused by it are astonishing. Not only will it cause direct losses such as energy, material consumption, and equipment failure, but carbon steel corrosion will also cause device leakage, Indirect losses such as material pollution, interruption of process flow, explosion and casualties, and environmental pollution. Therefore, the research on the improvement of the corrosion resistance...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C10/20
CPCC23C10/20
Inventor 张胜寒石荣雪张适宜
Owner NORTH CHINA ELECTRIC POWER UNIV (BAODING)