Catalytic wet oxidation catalyst and its preparation method

A catalytic wet oxidation, catalyst technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, chemical instruments and methods, etc., can solve the problem of unstable properties of amorphous alumina and sludge impurities Problems such as high content and non-repeatability

Active Publication Date: 2018-07-31
FUSHUN HUANKE PETROCHEM TECH DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method belongs to the process of physical mixing of alumina-containing species and activated carbon, and the dispersion of alumina and activated carbon is uneven; and the sludge used has high impurity content, and the obtained amorphous alumina is unstable, unrepeatable, and complex in structure

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Add solid aluminum chloride and chloroplatinic acid into distilled water while heating and stirring until dissolved to obtain solution (a). Add an appropriate amount of distilled water to the concentrated ammonia water and dilute it into about 10wt% dilute ammonia water (b). Powdered coconut shell charcoal is impregnated with Cu-Ce-containing impregnating solution, dried at 120°C for 240 minutes, roasted at 550°C under nitrogen protection for 4 hours, added to glucose aqueous solution and mixed evenly, the volume ratio of liquid to solid is 3:1, and then beaten with water, A slurry (c) is obtained. After adding (a) into the gelling tank and stirring and heating to 60°C, open the valve of the container containing (b), and control the system in the tank to drop to pH=4.0 within 10 minutes, then add (c), continue to add (b) dropwise, and control the dropwise addition of the tank system to pH=8.0 within 30 minutes. Keep the temperature at 60°C, pH=8.0, age for 1 hour, fil...

Embodiment 2

[0053]Add solid aluminum sulfate and rhodium nitrate into distilled water while heating and stirring until dissolved to obtain solution (a). Add an appropriate amount of distilled water to the concentrated ammonia water and dilute it into about 10wt% dilute ammonia water (b). Powdered coconut shell charcoal is impregnated with Cu-Ce-containing impregnating solution, dried at 120°C for 240 minutes, roasted at 550°C under nitrogen protection for 4 hours, added to glucose aqueous solution and mixed evenly, the volume ratio of liquid to solid is 3:1, and then beaten with water, Obtain activated carbon slurry (c). Take a plastic tank, add (a) into the tank, stir and heat to 60°C, open the valve of the container containing (b), control the system in the tank to drop to pH=4.0 within 10 minutes, open (c ) the valve of the container, continue to drop (b), control the dropwise addition of the system in the tank to pH=8.0 within 30 minutes, control the valve of the container of (c), an...

Embodiment 3

[0056] Add solid aluminum sulfate and rhodium nitrate into distilled water while heating and stirring until dissolved to obtain solution (a). The solid sodium metaaluminate is formulated to a concentration of 250g Al 2 o 3 / L sodium aluminate solution (b). Impregnate powdered coconut shell charcoal with an impregnating solution containing Fe-Ce, dry at 120°C for 240 minutes, and roast at 550°C for 4 hours under the protection of nitrogen, add sucrose aqueous solution and mix well, the volume ratio of liquid to solid is 3:1, and then add water for beating , to obtain slurry (c). The water glass is diluted in deionized water according to the ratio of 1:2 to prepare solution (d). Take a glue tank, put 2L of deionized water into it, stir and heat it to 60°C, then add the slurry (c), open the valve of the container containing (a) and (b) at the same time, control the pH of the system to 8.0, and control it for 45 minutes After dripping (a) inside, close the valve. Keep the tem...

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Abstract

The invention discloses a catalytic wet oxidation catalyst and a preparation method thereof. The catalyst includes the following core-shell structure component, the core-shell structure component is based on activated carbon loaded with transition metals and rare earth metals as the core, and uses noble metal-containing alumina or noble metal-containing amorphous silicon aluminum as the shell, and its preparation method It adopts co-precipitation method to prepare alumina or amorphous silicon-alumina and noble metal compound, and introduces activated carbon slurry loaded with transition metals and rare earth metals into the gelling process, and then obtains the catalyst through aging and other steps after gelling. The catalyst of the invention has high reactivity and stability in use.

Description

technical field [0001] The invention relates to a catalytic wet oxidation catalyst and a preparation method thereof, in particular to a noble metal catalyst for catalytic wet oxidation and a preparation method thereof. Background technique [0002] With the increasingly stringent global environmental protection regulations, the control indicators for sewage discharge standards are getting higher and higher. Under this form, wastewater catalytic oxidation treatment methods have been paid more and more attention to and adopted by people, such as the catalytic wet method of high-concentration sewage Oxidation, electrolytic catalytic oxidation, photocatalytic oxidation, advanced oxidation, etc. In the process of catalytic oxidation of wastewater, in order to obtain the ideal treatment effect and keep the cost of wastewater treatment low by reducing the reaction temperature and pressure, the preparation of cheap catalysts with high active components, high strength and high stabil...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/656B01J23/89C02F1/78C02F1/74C02F1/72
Inventor 蒋广安邓德刚单广波张晔刘雪玲李宝忠郭宏山刘忠生
Owner FUSHUN HUANKE PETROCHEM TECH DEV CO LTD
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