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Smelting process of nickel-based alloy containing aluminum, titanium, boron and zirconium

A nickel-based alloy, aluminum-titanium-boron technology, applied in the field of nickel-based alloy smelting process, can solve the problems of difficult control of the chemical composition of the alloy, affecting the overall performance of the alloy, and excessive addition at one time, so as to improve the durable performance and room temperature tensile strength. elongation, ensure alloy properties, and reduce segregation

Active Publication Date: 2017-11-24
SHANDONG ROITIE NEW MATERIAL SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Even if the temperature of the molten metal is suitable when aluminum and titanium are added, the chemical composition of the alloy is difficult to control due to burning loss and vacuum volatilization due to excessive addition at one time.
In addition, because aluminum, titanium, boron, and zirconium are light and have low density, they float on the surface of the molten metal after being added to the molten metal. If they are not stirred sufficiently, segregation will easily occur, which will seriously affect the comprehensiveness of the alloy. performance

Method used

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  • Smelting process of nickel-based alloy containing aluminum, titanium, boron and zirconium
  • Smelting process of nickel-based alloy containing aluminum, titanium, boron and zirconium
  • Smelting process of nickel-based alloy containing aluminum, titanium, boron and zirconium

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] According to the standard of K418B alloy, it is produced by the vacuum smelting process of the present invention, its chemical composition is shown in Table 1, and its performance parameters are shown in Table 2.

[0035] Taking the 200Kg vacuum furnace as an example, the vacuum smelting process of the present invention is as follows:

[0036] (1) The first step of carbon deoxidation:

[0037] Graphite, which accounts for 50% of the total carbon content of the superalloy, is added to the vacuum furnace crucible, placed at the bottom of the crucible, and all elements in the superalloy except aluminum, titanium, boron, zirconium, and nickel are added to the vacuum furnace crucible Carry out smelting; graphite is the particle that is crushed to 2-5mm by the spectral graphite electrode; the smelting temperature is 1570±10°C, and the smelting time is 25 minutes;

[0038] (2) The second step of carbon deoxidation:

[0039] When the temperature rises to 1580±10°C, add the re...

Embodiment 2

[0056] According to the standard of K418B alloy, it is produced by the vacuum smelting process of the present invention, its chemical composition is shown in Table 3, and its performance parameters are shown in Table 4.

[0057] Taking the 200Kg vacuum furnace as an example, the vacuum smelting process of the present invention is as follows:

[0058] (1) The first step of carbon deoxidation:

[0059] Graphite, which accounts for 50% of the total carbon content of the superalloy, is added to the vacuum furnace crucible, placed at the bottom of the crucible, and all elements in the superalloy except aluminum, titanium, boron, zirconium, and nickel are added to the vacuum furnace crucible Carry out smelting; graphite is the particle that is crushed to 2-5mm by the spectral graphite electrode; the smelting temperature is 1580±10°C, and the smelting time is 20min;

[0060] (2) The second step of carbon deoxidation:

[0061] When the temperature rises to 1570±10°C, add the remaini...

Embodiment 3

[0078] According to the standard of K418B alloy, it is produced by the vacuum smelting process of the present invention, its chemical composition is shown in Table 5, and its performance parameters are shown in Table 6.

[0079] Taking the 200Kg vacuum furnace as an example, the vacuum smelting process of the present invention is as follows:

[0080] (1) The first step of carbon deoxidation:

[0081] Graphite, which accounts for 50% of the total carbon content of the superalloy, is added to the vacuum furnace crucible, placed at the bottom of the crucible, and all elements in the superalloy except aluminum, titanium, boron, zirconium, and nickel are added to the vacuum furnace crucible Carry out smelting; graphite is the particle that is crushed to 2-5mm by the spectral graphite electrode; the smelting temperature is 1560±10°C, and the smelting time is 30 minutes;

[0082] (2) The second step of carbon deoxidation:

[0083] When the temperature rises to 1590±10°C, add the re...

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Abstract

Disclosed is a melting process for a nickel-based alloy containing aluminum, titanium, boron, and zirconium, comprising: adding graphite accounting for 50% of a total carbon-containing mass of an alloy into a crucible of a vacuum furnace and placing the graphite at the bottommost portion of the crucible, and adding all elements, except for aluminum, titanium, boron, zirconium, and nickel, in the alloy into the crucible of the vacuum furnace to be molten; raising the temperature, adding the remaining graphite into the crucible, and carrying out refining and then cooling; adding calcium metal into the crucible, and after the calcium metal is completely molten, carrying out refining and then cooling; adding aluminum and titanium into the crucible, and raising the temperature until the aluminum and the titanium are completely molten; adding a nickel-boron alloy and zirconium into the crucible, and raising the temperature until the nickel-boron alloy and the zirconium are completely molten; and cooling the molten metal, filtering, and carrying out tapping and pouring. The process method reduces the content of harmful gas and low-melting-point harmful impurities in an alloy, and achieves the purposes of purifying an alloy melt, reducing segregation of alloy elements, and ensuring alloy performance.

Description

technical field [0001] The invention relates to an alloy smelting process, in particular to a smelting process of a nickel-based alloy containing aluminum, titanium, boron and zirconium. Background technique [0002] The technical difficulty in vacuum smelting of aerospace and civilian high-temperature alloys lies in the strict control of the gas content (oxygen, nitrogen, hydrogen) in the alloy. At present, according to enterprise standards, the oxygen and nitrogen content in many alloys is generally around 20ppm. Only by reducing the content of harmful impurities in the alloy, reducing the segregation of alloy elements, and improving the purity of the alloy melt can the service performance and life of the alloy be improved. However, the vacuum smelting process is a very complex thermal processing process, and the design of any process step will have an important impact on the gas content, impurity content and properties of the alloy. [0003] O, N, and S in the alloy will...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/02C22C1/06C22C19/03
CPCC22C1/023C22C1/06C22C19/03C22C1/02
Inventor 李道乾刘玉庭郭建亭刘云王光华
Owner SHANDONG ROITIE NEW MATERIAL SCI & TECH