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Method for preparing low-pollution boards from municipal sludge and carbide slag

A technology of urban sludge and calcium carbide slag, applied in applications, ceramic products, household appliances, etc., can solve the problems of difficult long-term use, poor treatment, air pollution, etc., to improve the crystallization reaction rate, reduce the overflow of heavy metals, Density-enhancing effect

Inactive Publication Date: 2018-11-30
WUHAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] ① Municipal sludge contains a large amount of heavy metal ions, which will cause great harm to human life and production. As far as the current technology is concerned, there is no good solution, and sludge is blindly made into building materials Applied in daily production, as time goes by, the heavy metal ions in it will slowly leach out, causing harm to people's health
[0006] ② There are also a large amount of domestic garbage and urban pollutants in the urban sludge, which contain a large number of germs and harmful microorganisms. Not only is a lot of resources and fuel wasted, but also the harmful gas produced by incineration will pollute the air and cause serious harm to nearby people.
It uses sludge dehydrating agent and deodorant to dehydrate and deodorize sludge. Zhejiang Lvtian Environmental Engineering Co., Ltd. discloses a degradable sludge plastic environmental protection board and its preparation method (patent publication number: CN104591682A), It uses sludge, wood flour, PP powder, and various admixtures for secondary demoulding, granulation, and grouting. However, the durability and thermal insulation properties of the panels obtained by this method cannot be guaranteed, and this method is harmful to The heavy metal ions and organic matter in the sludge have not been well treated, only additives are added to fix them, and it is difficult to use them for a long time

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The wet base municipal sludge used in the present invention has an initial water content of ≥50wt.%, carbide slag is a slurry with a water content of ≤50wt.%, and the particle size of the crushed stone slag is 5mm≤r≤30mm.

[0023] The invention relates to a method for preparing boards from urban sludge and calcium carbide slag. The weight percentages of the raw materials are: 40wt.% wet base urban sludge, 20wt.% fly ash, 30wt.% Carbide slag, 10wt.% crushed stone slag, some amount of 2wt.% concentration of hydrogen peroxide and 42wt.% concentration of phosphoric acid mixture. The preparation process is as follows: wet-based municipal sludge is mixed with 2% concentration of hydrogen peroxide and 42% concentration of phosphoric acid solution, after stirring for 1 hour and standing for 24 hours, the heavy metal and phosphoric acid solution are absorbed and recovered by acidic cation exchange resin, and 18wt. % The sludge slurry is subjected to low-temperature pyrolysis and...

Embodiment 2

[0025] The wet-based urban sludge used in the present invention has an initial water content of ≥50wt.%, carbide slag is a slurry with a water content of ≤50wt.%, and the particle size of the crushed stone slag is 5mm≤r≤30mm.

[0026]The invention relates to a method for preparing boards from urban sludge and calcium carbide slag. The weight percentages of the raw materials are: 50wt.% wet basis urban sludge, 15wt% fly ash, 30wt% calcium carbide Slag, 5wt.% gravel slag, a certain amount of 2% concentration of hydrogen peroxide and 42% concentration of phosphoric acid mixed solution. The preparation process is as follows: wet-based urban sludge is mixed with 2wt.% concentration of hydrogen peroxide and 42wt.% concentration of phosphoric acid solution, stirred and reacted for 1 hour, and after standing for 24 hours, the heavy metal and phosphoric acid solution are recovered by acidic cation exchange resin adsorption. 15wt.% of the sludge is subjected to low-temperature cracking ...

Embodiment 3

[0028] The wet base municipal sludge used in the present invention has an initial water content of ≥50wt.%, carbide slag is a slurry with a water content of ≤50wt.%, and the particle size of the crushed stone slag is 5mm≤r≤30mm.

[0029] The invention relates to a method for preparing boards from urban sludge and calcium carbide slag. The weight percentages of raw materials are: 50wt%, wet base urban sludge, 10wt%, fly ash, 35wt%. Carbide slag, 5wt%. crushed stone slag, a certain amount of 2% concentration of hydrogen peroxide and 42% concentration of phosphoric acid mixed solution. The preparation process is as follows: wet-based municipal sludge is mixed with 2wt.% concentration of hydrogen peroxide and 42wt.% concentration of phosphoric acid solution, after stirring for 1 hour and standing for 24 hours, the heavy metal and phosphoric acid solution are recovered by acidic cation exchange resin adsorption, Take 20wt.% of the sludge slurry and undergo low-temperature pyrolysis...

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Abstract

The invention relates to a preparation method of sheet materials with low pollution by using city sludge and calcium carbide slags. Base materials which comprise city sludge with wet basis, coal ash, calcium carbide slags and broken stone slags are metered separately; firstly, heavy metal ions in the city sludge with wet basis are solidified, cracking and carbonization pretreatment is carried out for a part of the city sludge after solidification treatment, and the rest part of the city sludge after solidification treatment and calcium carbide slags are mixed in order to carry out pretreatment by a sintering method; the base materials after the pretreatment are mixed, and a compression molding is carried out for molding; after molding, drying is carried out till the weight is constant; a blank is placed in a microwave sintering apparatus, pumping is carried out in order to form vacuum, CO2 is introduced in order to keep the pressure in the system constant, and after maintenance, the sheet materials are obtained. The method has the beneficial effects that solidification effects of the heavy metal are good, the removal rates of various heavy metals are higher than 90%, and the removal rates are not limited by kinds of heavy metals; the utilization rate of solid wastes is high, and the sheet materials are widely suitable for usage in life and production.

Description

technical field [0001] The invention belongs to the technical field of sludge resource utilization, in particular to a method for preparing low-pollution boards by using urban sludge and carbide slag. Background technique [0002] Our country is a country with a lot of people and little land and resources are tight. In my country, with the continuous advancement of urbanization level construction, and from the national level to the general public, the awareness of environmental protection has become stronger and stronger. In recent years, the number of sewage treatment plants has increased sharply, and the resulting The amount of sludge (including various heavy metal ions, etc.) is also increasing. According to statistics, by 2020, my country's urban sludge discharge (dry weight) will reach 60 million tons. How to efficiently and rationally utilize these wastes and realize the rationalization and resource utilization of wastes has become an urgent problem to be solved at pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/08C04B30/00C04B18/30C04B18/04C04B20/04C04B40/02
CPCY02W30/91
Inventor 蹇守卫吴世明余后梁何桂海孙孟琪马保国肖慧权宗刚浮广明
Owner WUHAN UNIV OF TECH