A kind of high-strength antistatic composite material plate and its preparation method

A composite material, anti-static technology, applied in the direction of chemical instruments and methods, lamination, coating, etc., can solve the problems of explosion, high strength and high anti-static at the same time, and achieve a high degree of mechanization and strong designability , the effect of high rigidity

Active Publication Date: 2018-02-23
扬州润友复合材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But even so, there are some obvious deficiencies in the use of thermosetting resin-based composite materials. For example, when used in petrochemical, metallurgical and other occasions, it is often necessary for the board or its products to have high strength and antistatic properties at the same time. Deformation or static sparks, and may even explode in severe cases
Plates made of traditional thermosetting resin-based composite materials can have certain antistatic properties and strength properties, but often cannot achieve high strength and high antistatic properties at the same time

Method used

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  • A kind of high-strength antistatic composite material plate and its preparation method

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Experimental program
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Effect test

Embodiment 1

[0038] Embodiment 1: a kind of preparation method of high-strength antistatic composite material plate, its preparation process is:

[0039] (1) Weigh 1 part by weight of graphene, add it to 15 parts by weight of dimethylformamide, ultrasonically disperse for 1.5 hours, then add 0.3 parts by weight of triethylenetetramine and 0.3 parts by weight of dicyclohexyl carbonyl Imine, ultrasonic treatment for 15 minutes again, after reacting at 125°C for 45h, adding 4 parts by weight of ethanol, standing for 54h, filtering, washing the obtained precipitate, and vacuum drying at 60°C for 42h to obtain modified graphene;

[0040] (2) Prepare a dilute sulfuric acid solution with a concentration of 15% by mass, immerse all the copper powder in the dilute sulfuric acid solution, ensure that the liquid level of the dilute sulfuric acid exceeds the copper powder by 15cm, sonicate for 45min, then let stand for 36h, then sonicate again for 45min , filter to remove the sulfuric acid solution, t...

Embodiment 2

[0051] Embodiment 2: A kind of preparation method of high-strength antistatic composite material plate, its preparation process is:

[0052] (1) Weigh 1 part by weight of graphene, add it to 10 parts by weight of dimethylformamide, ultrasonically disperse for 1 hour, then add 0.2 part by weight of triethylenetetramine and 0.1 part by weight of dicyclohexylcarbonyl Amine, again sonicated for 10 min, reacted at 120°C for 40h, added 3 parts by weight of ethanol, stood still for 48h, filtered, washed the obtained precipitate, and vacuum dried at 55°C for 36h to obtain modified graphene;

[0053] (2) Prepare a dilute sulfuric acid solution with a concentration of 10% by mass, immerse all the copper powder in the dilute sulfuric acid solution, ensure that the liquid level of the dilute sulfuric acid exceeds the copper powder by 10cm, sonicate for 30min, then let stand for 24h, then sonicate again for 30min , filter to remove the sulfuric acid solution, then rinse the copper powder w...

Embodiment 3

[0064] Embodiment 3: a kind of preparation method of high-strength antistatic composite material plate, its preparation process is:

[0065] (1) Weigh 1 part by weight of graphene, add it to 20 parts by weight of dimethylformamide, ultrasonically disperse it for 2 hours, then add 0.4 part by weight of triethylenetetramine and 0.5 part by weight of dicyclohexylcarbonyl Amine, ultrasonic treatment for 20min again, after reacting at 130°C for 50h, adding 5 parts by weight of ethanol, standing for 60h, filtering, washing the obtained precipitate, and vacuum drying at 65°C for 48h to obtain modified graphene;

[0066] (2) Prepare a dilute sulfuric acid solution with a concentration of 20% by mass, immerse all the copper powder in the dilute sulfuric acid solution, ensure that the liquid level of the dilute sulfuric acid exceeds the copper powder by 20cm, sonicate for 60min, then let it stand for 48h, then sonicate again for 60min , filter to remove the sulfuric acid solution, then ...

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Abstract

The invention discloses a high-strength antistatic composite material sheet. The high-strength antistatic composite material sheet comprises composite material outer structure layers and a conductive core layer. The conductive core layer is located between the upper and lower outer structure layers. The outer structure layer is prepared from unsaturated polyester resin, methyl ethyl ketone peroxide, cobaltous naphthenate, modified graphene and a glass fiber cloth through compounding. The conductive core layer is prepared from unsaturated polyester resin, methyl ethyl ketone peroxide, cobaltous naphthenate, organized copper powder, carboxyl-terminated liquid nitrile rubber, dibutyl phthalate and a glass fiber mat through compounding. The preparation method is convenient. The traditional composite material molding technology can be used for production and processing without improvement. In production, a degree of mechanization is high, labor is reduced and a production cost is low. The high-strength antistatic composite material sheet has good mechanical properties, conductive performances and antistatic performances, can be used at a high temperature for a long time, has large rigidity and creep resistance, does not produce deformation, has good designability and can be used for petrochemical engineering and metallurgy occasions with high-strength antistatic composite material sheet use demands and high strength and antistatic performance requirements.

Description

technical field [0001] The invention discloses a composite material plate, in particular to a high-strength antistatic composite material plate and a production method thereof. Background technique [0002] Thermosetting resin-based composite materials use thermosetting resins, including unsaturated polyester resins, epoxy resins, etc. Reinforced material is a kind of composite material made by certain processing technology. It has the advantages of strong designability, anti-corrosion, and convenient processing and molding. The composite material sheet made of it can be widely used in construction, municipal administration, transportation, packaging and other fields. But even so, there are some obvious deficiencies in the use of thermosetting resin-based composite materials. For example, when used in petrochemical, metallurgical and other occasions, it is often required that the board or its products used have high strength and antistatic properties at the same time. Defo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/06C08K13/06C08K9/04C08K9/06C08K3/04C08K5/14C08K5/098C08K7/14C08K3/08C08K5/12
CPCB32B5/02B32B5/26B32B37/10B32B2250/20B32B2255/02B32B2255/26B32B2262/101B32B2307/202B32B2307/21C08K3/04C08K5/098C08K5/14C08K7/14C08K9/04C08K13/06C08L67/06C08L2201/04C08L13/00C08K9/06C08K2003/085C08K5/12
Inventor 徐致伟宋小雨王静
Owner 扬州润友复合材料有限公司
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